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Zeolite-like Topology Oxonitridosilicate LaBaSiNO with Potential Applications in Nonlinear Optical Materials. | LitMetric
A novel zeolite-like topology oxonitridosilicate LaBaSiNO with the space group 2 (no. 38) and lattice parameters = 9.5193 (3) Å, = 16.7011 (5) Å, = 26.0279 (8) Å, and = 12 has been synthesized by a high-temperature solid-state reaction. The crystal structure of LaBaSiNO has four different kinds of tiling, and the cages in the structure are filled with La, Ba, and O atoms. The presence of a noncentrosymmetric space group further suggests its potential for nonlinear optical (NLO) applications, and LaBaSiNO demonstrated a stronger second-harmonic generation (SHG) response than that of SiO.
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