Double Nanohole Plasmonic Tweezers (DNH) have emerged as a powerful approach for confining light to sub-wavelength volume, enabling the trapping of nanoscale particles much smaller than the wavelength of light. However, to circumvent plasmonic heating effects, DNH tweezers are typically operated off-resonance, resulting in reduced optical forces and field enhancements. In this study, we introduce a novel DNH design with a reflector layer, enabling on-resonance illumination while minimizing plasmonic heating. This design efficiently dissipates heat and redistributes the electromagnetic hotspots, making them more accessible for trapping nanoscale particles and enhancing light-matter interactions. We also demonstrate low-power trapping and release of small extracellular vesicles. Our work opens new possibilities for trapping-assisted Surface Enhanced Raman Spectroscopy (SERS), plasmon-enhanced imaging, and single photon emission applications that demand strong light-matter interactions.
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http://dx.doi.org/10.1021/acs.nanolett.3c02543 | DOI Listing |
Sci Rep
January 2025
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, 30332, USA.
Nanoscale Fourier transform infrared (Nano-FTIR) imaging and spectroscopy correlated with photoluminescence measurements of lunar Apollo samples with different surface radiation exposure histories reveal distinct physical and chemical differences associated with space weathering effects. Analysis of two sample fragments: an ilmenite basalt (12016) and an impact melt breccia (15445) show evidence of intrinsic or delivered Nd and an amorphous silica glass component on exterior surfaces, whereas intrinsic Cr and/or trapped electron states are limited to interior surfaces. Spatially localized 1050 cm/935 cm band ratios in Nano-FTIR hyperspectral maps may further reflect impact-induced shock nanostructures, while shifts in silicate band positions indicate accumulated radiation damage at the nanoscale from prolonged space weathering due to micrometeorites, solar wind, energetic x-rays and cosmic ray bombardment.
View Article and Find Full Text PDFNanoscale
January 2025
School of Chemical Engineering, Yeungnam University, Gyeongsan, 38541, South Korea.
Eliminating hazardous antibiotics from aquatic environments has become a major concern in recent years. Tetracycline (TC) compounds pose a challenge for the selective degradation of harmful chemical groups. In this study, we successfully designed carbon vacancies in a gCN@WC (GW) heterostructure for the effective removal of TC pollutants under visible light.
View Article and Find Full Text PDFLangmuir
January 2025
Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 182 21 Prague 8, Czech Republic.
Black aluminum is a material characterized by high surface porosity due to columnar growth and exhibits unique optical properties that make it attractive for applications such as light trapping, infrared detection, and passive thermal radiation cooling. In this study, we correlate the structural and optical properties of black aluminum by comparing it with conventional reflective aluminum layers. These layers of varying thicknesses were deposited on fused silica substrates, and their optical properties were analyzed.
View Article and Find Full Text PDFSci Adv
January 2025
Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996, USA.
Metastable phases can exist within local minima in the potential energy landscape when they are kinetically "trapped" by various processing routes, such as thermal treatment, grain size reduction, chemical doping, interfacial stress, or irradiation. Despite the importance of metastable materials for many technological applications, little is known about the underlying structural mechanisms of the stabilization process and atomic-scale nature of the resulting defective metastable phase. Investigating ion-irradiated and nanocrystalline zirconia with neutron total scattering experiments, we show that metastable tetragonal ZrO consists of an underlying structure of ferroelastic, orthorhombic nanoscale domains stabilized by a network of domain walls.
View Article and Find Full Text PDFNanotechnology
December 2024
College of Nanoscale Science and Engineering, State University of New York at Albany, NFS 234, 215 Fuller Road, Albany, NY 12203, USA, Albany, 12203, UNITED STATES.
GaN is an important semiconductor for energy-efficient light-emitting devices. Hydrogen plays a crucial role in gallium nitride (GaN) growth and processing. It can form electrically neutral complexes with acceptors during growth, which significantly increases the acceptor incorporation.
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