An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η to η.
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Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center.
Dalton Trans
January 2024
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.
An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η to η.
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