Facile preparation of near-monodisperse oligocellulose and its elastomeric derivatives with tunable mechanical properties.

Oligocellulose (OC) with low polydispersity indices has been produced in large quantities using an improved method of acid-assisted hydrolysis, in which long cellulose chains disintegrate in concentrated phosphoric acid at moderately elevated temperatures. The hydrolysis time has been reduced by three orders of magnitude without compromising the overall yield of the process or the quality of OC products. The efficient production of high-quality OCs in large quantities allows for developing OC-derived elastomeric materials. A series of OC-graft-poly(isobornyl methacrylate-random-n-butyl acrylate) [OC-g-P(IBOMA-r-BA)] elastomers have been synthesized via activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP). OC-g-P(IBOMA-r-BA) elastomers have tunable molecular architectures and phase morphologies toward desirable mechanical properties and thermal stability suitable for various applications. The methodologies of the OC production and the graft-polymers synthesis in this study would help advance technologies for broader applications of bio-based elastomers.