The Lorenz system was derived on the basis of a model of convective atmospheric motions and may serve as a paradigmatic model for considering a complex climate system. In this study we formulated the thermodynamic efficiency of convective atmospheric motions governed by the Lorenz system by treating it as a nonequilibrium thermodynamic system. Based on the fluid conservation equations under the Oberbeck-Boussinesq approximation, the work necessary to maintain atmospheric motion and heat fluxes at the boundaries were calculated. Using these calculations, the thermodynamic efficiency was formulated for stationary and chaotic dynamics. The numerical results show that for both stationary and chaotic dynamics, the efficiency tends to increase as the atmospheric motion is driven out of thermodynamic equilibrium when the Rayleigh number increases. However, it is shown that the efficiency is upper bounded by the maximum efficiency, which is expressed in terms of the parameters characterizing the fluid and the convective system. The analysis of the entropy generation rate was also performed for elucidating the difference between the thermodynamic efficiency of conventional heat engines and the present atmospheric heat engine. It is also found that there exists an abrupt drop in efficiency at the critical Hopf bifurcation point, where the dynamics change from stationary to chaotic. These properties are similar to those found previously in the Malkus-Lorenz waterwheel system.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevE.108.044201 | DOI Listing |
Chem Asian J
January 2025
Institut po elektronikа Akad Emil Džakov B'lgarska akademiâ na naukite: Institut po elektronika Akademik Emil Dzakov B'lgarska akademia na naukite, Vihren Tautomeric devises and sensors, BULGARIA.
Dithienylethenes (DTE) are a rare class of photoswitches, which are capable of undergoing a fast photochemical cyclization leading to increased aromaticity of the closed isomer. At the same time in most of the tautomeric compounds the tautomeric state is strongly affected by the change in the aromaticity of the involved aromatic rings. Very recently it has been shown that the implementation of DTE moiety in salicylideneaniline leads to switching of the stable open form enol tautomer to thermodynamically stable keto tautomer upon cyclization.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Radiotherapy, The Second Hospital of Jilin University, Changchun 130041, P. R. China.
Polynitrogen with high energy and environmental friendliness has exhibited potential application in military and civilian fields. In this study, first-principle calculations were employed to conduct a comprehensive investigation of the nitrogen-rich Lu-N compounds. The research yielded ten novel polynitrides: 2/-LuN, 1̅-LuN, 1̅-LuN, 2/-LuN, 1̅-LuN, 1̅-LuN, 1̅-LuN, -LuN, 4/-LuN, and -LuN.
View Article and Find Full Text PDFPhysiol Plant
January 2025
College of Agronomy, Jilin Agricultural University, Jilin, P. R. China.
Combined cold and high moisture stress (CHS) is a prevalent abiotic stress during maize sowing in northeast China, severely affecting the growth of seedlings and seed germination. However, the mechanism underlying seed growth responses to CHS remains unclear. We used Jidan441 (JD441, CHS-resistant) and Jidan558 (JD558, CHS-sensitive) as experimental materials.
View Article and Find Full Text PDFNanoscale
January 2025
School of Physics, Hunan Key Laboratory of Super Microstructure and Ultrafast Process, Hunan Key Laboratory of Nanophotonics and Devices, State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China.
Solid-state refrigeration technology, which utilizes phase transition materials responsive to an external field through which heat is exchanged with the environment, serves as a promising alternative to traditional vapor-compression refrigeration technologies. However, many existing solid-state refrigeration materials are limited by low latent heat, large external driving forces, high thermal hysteresis, or low thermal conductivity, limiting practical applications. In this work, through molecular dynamics simulations and thermodynamic analysis, we predict giant inverse elastocaloric effects in the composited alkane and carbon nanotube/graphene architectures.
View Article and Find Full Text PDFRSC Adv
January 2025
Research Laboratory in Subterranean and Surface Hydraulics, University of Biskra PO Box 145 RP Biskra Algeria.
This investigation aims to apply the adsorption process to eliminate mequitazine and ethinylestradiol, the active molecules of Primalan and Diane, respectively, from aqueous solutions, utilizing biochar synthesized from pumpkin fruits (PB-500). The results revealed that the obtained adsorbent possessed a notable specific surface area, contributing to removal efficiencies of 66.61% and 62.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!