Photoinduced silylation of silanes with 2-aryl-2-indazoles was developed under mild conditions, which could efficiently result in diverse 3-silylated 2-indazoles with good substrate scopes. A series of scaled-up to gram level and radical capture operations were performed in this system. Meanwhile, a bioactive molecule was tolerated well under typical conditions.
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| http://dx.doi.org/10.1021/acs.joc.3c02232 | DOI Listing |
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