Invited for the cover of this issue is the group of Selvan Demir at the Michigan State University. The cover art depicts the helicopter landing of the first crystallographically characterized bismolyl anion potassium salt in a desert oasis landscape with pyramids of elemental bismuth. Read the full text of the article at 10.1002/chem.202302687.
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From an Isolable Bismolyl Anion to an Yttrium-Bismolyl Complex with μ-Bridging Bismuth(I) Centers and Polar Covalent Y-Bi Bonds.
Chemistry
December 2023
Department of Chemistry, Michigan State University, East Lansing, MI, 48824, USA.
Invited for the cover of this issue is the group of Selvan Demir at the Michigan State University. The cover art depicts the helicopter landing of the first crystallographically characterized bismolyl anion potassium salt in a desert oasis landscape with pyramids of elemental bismuth. Read the full text of the article at 10.
View Article and Find Full Text PDFFrom an Isolable Bismolyl Anion to an Yttrium-Bismolyl Complex with μ-Bridging Bismuth(I) Centers and Polar Covalent Y-Bi Bonds.
Chemistry
December 2023
Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA.
The synthesis and first structural characterization of the [K(18-crown-6)] bismolyl Bi (C Me Bi) contact ion pair (1) is presented. Notably, according to Natural Resonance Theory calculations, the Bi anion of 1 features two types of leading mesomeric structures with localized anionic charge and two lone pairs of electrons at the Bi center, as well as delocalized anionic charge in the π-conjugated C Bi ring. The lone pairs at Bi enable a unique bridging coordination mode of the bismolyl ligand, as shown for the first rare earth metal bismolyl complex (Cp Y) (μ-η -Bi ) (2).
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