Carbon-carbon σ-single bonds are crucial for constructing molecules like ethane derivatives (RC-CR), which are composed of tetrahedral four-coordinate carbons. Molecular functions, such as light absorption or emission, originate from the π-bonds existing in ethylene derivatives (RC═CR). In this study, a relatively stable cyclopentane-1,3-diyl species with π-single bonding system (C-π-C) with planar four-coordinate carbons is constructed. This diradicaloid is energetically more stable than the corresponding σ-single bonding system. The π-electron single bonding system provides deeper insights into the chemical bonding and the physical properties derived from the small energy gaps between the bonding and antibonding molecular orbitals.
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