With both ferrocene and air as the redox catalysts, for the first time, the low-cost natural ilmenite (FeTiO) was successfully used for photocatalytic bond formations. Under the assistance of a traceless H-bond, and HCHO as the methylene reagent, a variety of imidazo[1,5-]quinoxalinones were semi-heterogeneously photosynthesized in high yields with good functional group compatibility.
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Ferrocene/air double-mediated FeTiO-photocatalyzed semi-heterogeneous annulation of quinoxalin-2(1)-ones in EtOH/HO.
Chem Commun (Camb)
November 2023
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China.
With both ferrocene and air as the redox catalysts, for the first time, the low-cost natural ilmenite (FeTiO) was successfully used for photocatalytic bond formations. Under the assistance of a traceless H-bond, and HCHO as the methylene reagent, a variety of imidazo[1,5-]quinoxalinones were semi-heterogeneously photosynthesized in high yields with good functional group compatibility.
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