Kagome lattice provides a distinctive platform to investigate various correlated electron orders. Recently, an unconventional charge density wave (CDW) with novel chirality is observed in the kagome metalVSb(= K, Rb, Cs), and the origin of which is still unclear. Here, using a tight-binding model and the mean-field method, we calculate the electron order in the quasi-two-dimensional kagome lattice with 1/3 electron filling, and show that the chiral CDW emerges under a set of parameters withC6rotational symmetry but without mirror symmetry. Physically, the reason why we choose this set of parameters is based on the possible tangential distortion of the kagome lattice. Our results provide a fresh insight to understand the microscopic origin of the unconventional CDW inVSb.
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http://dx.doi.org/10.1088/1361-648X/ad0cae | DOI Listing |
Nanotechnology
January 2025
Departamento de Física, Universidade Federal do Ceará, Campus do Pici, Bloco 922, 60455-900, Fortaleza, 60455-900, BRAZIL.
We investigate the electronic properties of nanoribbons made out of monolayer Lieb, transition, and kagome lattices using the tight-binding model with a generic Hamiltonian. It allows us to map the evolutionary stages of the interconvertibility process between Lieb and kagome nanoribbons by means of only one control parameter. Results for the energy spectra, the density of states, and spatial probability density distributions are discussed for nanoribbons with three types of edges: straight, bearded, and asymmetric.
View Article and Find Full Text PDFAdv Mater
December 2024
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA, 15260, USA.
Magnetoplumbites are one of the most broadly studied families of hexagonal ferrites, typically with high magnetic ordering temperatures, making them excellent candidates for permanent magnets. However, magnetic frustration is rarely observed in magnetoplumbites. Herein, the discovery, synthesis, and characterization of the first Mn-based magnetoplumbite, as well as the first magnetoplumbite involving pnictogens (Sb), ASbMnO (A = K or Rb) are reported.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China.
Alkali element doping has significant physical implications for two-dimensional materials, primarily by tuning the electronic structure and carrier concentration. It can enhance interface electronic interactions, providing opportunities for effective charge transfer at metal-organic interfaces. In this work, we investigated the effects of gradually increasing the level of K doping on the lattice structure and electronic properties of an organometallic coordinated Kagome lattice on a Ag(111) surface.
View Article and Find Full Text PDFAcc Chem Res
December 2024
Faculty of Chemistry and Food Chemistry, TU Dresden, Bergstrasse 66c, 01069 Dresden, Germany.
ConspectusTriangulene (TRI) and its heterotriangulene (HT) derivatives are planar, triangle-shaped molecules that, via suitable coupling reactions, can form extended organic two-dimensional (2D) crystal (O2DC) structures. While TRI is a diradical, HTs are either closed-shell molecules or monoradicals which can be stabilized in their cationic form.Triangulene-based O2DCs have a characteristic honeycomb-kagome lattice.
View Article and Find Full Text PDFJ Phys Condens Matter
December 2024
Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab 140306, India.
Orbitronics and valleytronics, analogous to spintronics, leverage the orbital degree of freedom and the valley degree of freedom of electrons to carry information, promising significant advancements in information processing. In this study, we disentangle the orbital and valley Nernst effect (VNE) in 2D monolayers, based on the global symmetry of the monolayers. We conduct an in-depth analysis of the orbital (valley) Nernst effect in inversion symmetric (asymmetric) monolayers, using an analytical tight binding model.
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