In order to overcome the defects of fast-growing poplar wood, such as low strength and poor toughness, this paper introduces a method of modifying poplar wood via impregnation with silica sol/melamine-glyoxal (silica sol/MG) resin and explores its effects on the physical, mechanical, and thermal properties of poplar wood. It was found via scanning electron microscopy that the composite modifier covered and filled the cell lumen, cell interstitial space, and cell wall pores of poplar wood. Further, infrared spectroscopy and X-ray photoelectron spectroscopy analyses confirmed that chemical cross-linking occurred between the silica sol/MG resin composite modifier and the internal groups of poplar wood and that the Si-O-Si flexible long chains introduced in the composite modifier formed a cross-linking network with poplar wood such as Si-O-Si and Si-O-C, which led to the improvement of the physical and mechanical properties and the enhancement of the thermal stability of poplar wood. The method provides a theoretical basis for the high-value utilization of fast-growing poplar wood.
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http://dx.doi.org/10.3390/polym15214247 | DOI Listing |
ChemSusChem
December 2024
Guangxi University, School of Light Industrial and Food Engineering, 100 East University Road, 530004, Nanning, CHINA.
Separation of lignin by pretreatment is an important step in biomass refining. This study investigated how a novel dicarboxylic acid-based deep eutectic solvent (DES) - choline chloride (ChCl)/malonic acid (MA) - affected the process of separating lignin from poplar. At 140°C for 3.
View Article and Find Full Text PDFPlant Physiol
December 2024
State Key Laboratory of Subtropical Silviculture, College of Forestry and Biotechnology, Zhejiang A&F University, Hangzhou 311300, China.
Tension wood (TW), characterized by increased cambium cell proliferation and few vessels, is a classical model for the mechanical analysis of wood formation. In this study, we found higher superoxide anion (O2.-) levels in the cambium zone of poplar (Populus alba × P.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
This study investigates lignin's influence on the hygroscopic behavior of poplar wood. Delignification was achieved using an acidic NaClO solution, and digital image correlation (DIC) was employed to measure strain distribution during shrinking and swelling across relative humidity (RH) ranging of 0 % to 97 %. Results showed that lignin removal increased equilibrium moisture content (EMC) by up to 3.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Materials Science and Applied Chemistry, Institute of Polymer Materials, Riga Technical University, 3/7 Paula Valdena Street, LV-1048 Riga, Latvia.
Using a pilot-scale chamber with an interior capacity of 340 L, European aspen () wood boards were thermally modified (TM) under pressure in nitrogen at a maximum temperature of 160-170 °C, for 60-180 min, and with an initial nitrogen pressure of 4-5 bar. After the TM process, aspen wood was characterised by dimensional changes, mass loss (ML), equilibrium moisture content (EMC), antiswelling efficiency (ASE), cell wall total water capacity (CWTWC), modulus of rupture (MOR), modulus of elasticity (MOE), and Brinell hardness (BH). This work offers fresh insights into the characteristics of aspen wood following a closed TM process in pressurised nitrogen.
View Article and Find Full Text PDFPlant Cell Rep
December 2024
Forestry College, Inner Mongolia Agricultural University, No. 306, Zhaowuda Road, Hohhot, 010018, People's Republic of China.
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