Activate hydrogen peroxide for facile and efficient removal of aflatoxin B by magnetic Pd-chitosan/rice husk-hercynite biocomposite and its impact on the quality of edible oil.

Due to the high heat and chemical stability of aflatoxin B1 (AFB) with significant impacts on humans/animals and thus it needs to develop a practical and efficient approach for its removal. Herein, we fabricated a magnetic Pd-chitosan/glutaraldehyde/rice husk/hercynite (Pd@CRH-x) composite for efficient detoxification of AFB. The Pd@CRH-x was obtained by a simple wet-impregnation procedure of CRH complexes followed by pyrolysis. The results confirmed that the unique structure of Pd@CRH-400 effectively improves dispersity, and mass transfer subsequently enhancing removal efficiency in batch conditions. Results indicate 94.30 % of AFB was efficiently degraded by 0.1 mg mL Pd@CRH-400 with 4.0 mM HO at wide pH ranges (3.0-10) at 60 min with a decomposition rate constant of 0.0467 min. Besides, by comparing the quality factors of edible oil (i.e., acid value, peroxide value, iodine value, moisture, volatile matters, anisidine value, and fatty acid composition), it was confirmed that there was no obvious influence on the physicochemical indicators of edible oil after removal/storage process. Subsequently, the systematic kinetic study and AFB degradation mechanism were presented. This study provides a new strategy for the efficient construction of controllable and dispersed Pd-based catalysts using CRH-x as a spatial support for alleviating the risk of toxic pollutants.