A visible-light-driven, photocatalyst-free, air-assisted carbon cleavage of dienes was achieved. Photochemical editing of dienes via an electron donor-acceptor (EDA) complex facilitates direct access to cyclopropane derivatives. This innovative methodology creates an opportunity for the efficient access to valuable cyclopropane derivatives under mild and ambient conditions.
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| http://dx.doi.org/10.1021/acs.orglett.3c03317 | DOI Listing |
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