A 3D Co-based metal-organic framework has been prepared, which contains a bis(triarylamine) with terphenyl units as a redox-active linker. Manipulation of the redox events the electrochemical method confirmed that charge hopping is dominant within the 3D framework. Investigation of the spectroelectrochemical properties within the structure leads to the formation of mono and dual radical cations obtained reversibly in two-steps due to the presence of two redox-active sites.
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Exploring redox properties of a 3D Co-based framework with bis(triarylamine) terphenyl as a redox-active linker.
Chem Commun (Camb)
November 2023
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan.
A 3D Co-based metal-organic framework has been prepared, which contains a bis(triarylamine) with terphenyl units as a redox-active linker. Manipulation of the redox events the electrochemical method confirmed that charge hopping is dominant within the 3D framework. Investigation of the spectroelectrochemical properties within the structure leads to the formation of mono and dual radical cations obtained reversibly in two-steps due to the presence of two redox-active sites.
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