Low-temperature, ultra-fast, and recyclable self-healing nanocomposites reinforced with non-solvent silylated modified cellulose nanocrystals.

Developing polymeric materials with remarkable mechanical properties and fast self-healing performance even at low temperatures is challenging. Herein, the polymeric nanocomposites containing silane-treated cellulose nanocrystals (SCNC) with ultrafast self-healing and exceptional mechanical characteristics were developed even at low temperatures. First, CNC is modified with a cyclic silane coupling agent using an eco-friendly chemical vapor deposition method. The nanocomposite was then fabricated by blending SCNC with matrix prepolymer, prepared from monomers that possess lower critical solution temperature, followed by the inclusion of dibutyltin dilaurate and hexamethylene diisocyanate. The self-healing capability of the novel SCNC/polymer nanocomposites was enhanced remarkably by increasing the content of SCNC (0-3 wt%) and reaching (≥99 %) at temperatures (5 & 25 °C) within <20 min. Moreover, SCNC-3 showed a toughness of (2498 MJ/m) and SCNC-5 displayed a robust tensile strength of (22.94 ± 0.4 MPa) whereas SCNC-0 exhibited a lower tensile strength (7.4 ± 03 MPa) and toughness of (958 MJ/m). Additionally, the nanocomposites retain their original mechanical properties after healing at temperatures (5 & 25 °C) owing to the formation of hydrogen bonds via incorporation of the SCNC. These novel SCNC-based self-healable nanocomposites with tunable mechanical properties offer novel insight into preparing damage and temperature-responsive flexible and wearable devices.