The special structure of perovskite-like compounds allows the existence of some open spaces in the crystals that play an important role in their crystal function enhancement and can accommodate active oxygen, which helps to solve some problems in the field of corrosion prevention. The magnetic lanthanum cuprate was obtained through the doping of Co and Sr, and compared with LaCuO and epoxy resin, its corrosion resistance was improved by 215.2 and 566.7%, respectively. The micromagnetic field in the crystal interfered with the state of motion of the electrons and prolonged their transport path. High concentration doping and substitution of unequal states led to the formation of oxygen vacancy defects, which could trap active oxygen molecules and inhibit cathodic corrosion reactions. The unique alternating interlayer structure of perovskite-like compounds was conducive to the release of Cu, thus forming a more stable passivator on the surface of the coating. LaSrCuCoO had both magnetic properties and structural advantages, which enhanced the shielding property of epoxy resin and expanded the application of perovskite-like compounds in the field of corrosion prevention.
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http://dx.doi.org/10.1021/acsami.3c09858 | DOI Listing |
Inorg Chem
October 2024
Martin-Luther-University Halle-Wittenberg, Department of Chemistry, Inorganic Chemistry, Kurt-Mothes-Straße 2, D-06120 Halle, Germany.
Ruddlesden-Popper (RP) compounds of the general formula (AX)(ABX) with their unique sequence of perovskite-like (ABX) and rock-salt-like units (AX) promise applications in diverse fields such as catalysis and superconductivity. Fluorination of RP oxides often leads to dramatic changes in the material properties, caused by differences in the atomic and electronic structure. While current research focuses on fluorination of = 1 type RP oxides (ABO), = 3 RP oxyfluorides have remained elusive.
View Article and Find Full Text PDFDalton Trans
August 2024
Solid State and Materials Laboratory, Department of Chemistry, National Institute of Technology, Rourkela-769008, India.
Antimony/bismuth-based organic-inorganic hybrid halide perovskite-like compounds have generated enormous research interest due to their excellent optical properties. Exploration of new compounds and understanding of their structural stability and optoelectronic properties is of utmost importance for practical applications of these materials. We report two new 0D perovskite-like compounds and their solid solution, (CHNH)BiSbI, having propyl amine as the spacer cation and iodine as the halide ion.
View Article and Find Full Text PDFNanoscale
June 2024
Center for Research in Nanotechnology and Science, Indian Institute of Technology Bombay, Powai, Mumbai, 400076-India.
With the rapid development of technology, the development of self-powered sensors has garnered significant attention. The importance of monitoring humidity has grown significantly in various technological contexts, from environmental monitoring to biomedical applications. In this work, we have fabricated a low-cost and self-powered humidity sensor using zero-dimensional perovskite-like structures.
View Article and Find Full Text PDFDalton Trans
March 2024
Department of Materials Science and Engineering, Kyoto University, Yoshida Honmachi, Sakyo-ku, Kyoto, 606-8501, Japan.
We previously reported that Zr substitution improves the chemical stability of BaYO and nominally 20 mol% Zr-substituted BaYO is an oxide-ion conductor at intermediate temperatures (500-700 °C). However, the influence of Zr substitution on the structural properties of BaYO was poorly understood. This paper aims to comprehensively understand the crystal structure of BaYO with Zr substitution by powder X-ray diffraction (XRD), extended X-ray absorption fine structure (EXAFS) measurements, and first-principles calculations.
View Article and Find Full Text PDFChem Asian J
April 2024
New Chemistry Unit, International Centre for Materials Science, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur, Bangalore, 560064, India.
Low-dimensional hybrid bismuth halide perovskites have recently emerged as a class of non-toxic alternative to lead perovskites with promising optoelectronic properties. Here, we report three hybrid bismuth(III)-iodides: 0-D (HDAC)BiI ⋅ 6HO (HDAC_Bi_I), 0-D (HDAF)BiI ⋅ 2I ⋅ 2I ⋅ 6HO (HDAF_Bi_I), and 1-D (HDAP)BiI (HDAP_Bi_I) (where HDAC=trans-1,4-diammoniumcyclohexane; HDAF=2,7-diammoniumfluorene and HDAP=1,5-diammoniumpentane). Their synthesis, single-crystal X-ray structures, and photophysical properties are reported.
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