The spin-lattice relaxation time has been studied trough alternating-current susceptometry and ultralow-frequency Raman spectroscopy in a family of silver(II)-derived molecular systems with spin / and formulas [Ag(-CTH)(NO)] () and [Ag(-CTH)(ClO)] (), where CTH = -5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane. The combination of both techniques demonstrates the occurrence of slow spin magnetic relaxation induced by spin-phonon interaction. The magnetic behavior of these silver(II)-derived systems opens the door to a new cation in the scarce family of = / systems with slow relaxation of magnetization.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664066 | PMC |
| http://dx.doi.org/10.1021/acs.inorgchem.3c02265 | DOI Listing |
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