Ultrahigh Efficient Collection of Underwater Bubbles by High Adsorption and Transport, Coalescence, and Collection Integrating a Conical Arrayed Surface.

The capture and utilization of underwater fuel bubbles such as methane can alleviate the greenhouse effect, solve the global energy crisis, and possibly improve the endurance of underwater equipment. However, previous research routinely failed to achieve the integrated process of continuous adsorption, transportation, and collection of bubbles limited by the trade-off between the bubble adhesion and transport efficiency dependent on interfacial pinning, tremendously hindering the direct capture and utilization of underwater fuel bubbles. To break through this bottleneck, a magnetic-guided conical arrayed surface (CAS) associated with a laser etching technique is fabricated conveniently to realize superhydrophobicity. The bubbles on laser-etched CAS have higher adhesiveness and low-pinning transport compared with those on the nonlaser-etched surface. Intriguingly, the gas film adsorbed within the CAS seems to be a gas channel, which accelerates the bubble coalescence and fast spreading to eventually realize the integration of transport, coalescence, and collection. The dynamic behaviors of bubble adsorption, transportation, and coalescence on CAS are probed to reveal the mechanism of the gas film-generating process within conical arrays. Furthermore, a novel underwater bubble-collecting device with multiangled CAS is proposed to achieve multidirectional capture, highly efficient transportation, and collection of rising bubbles. The results advance our understanding of dynamic behaviors of bubbles at solid-liquid interfaces and facilitate design and manufacturing of an apparatus for bubble collection.