The title compound, {[Ni(CHO)(CHNO)]·HO}, contains octa-hedrally coordinated Ni ions ligated by 1,3-adamantanedi-acetato (ada) ligands and -(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni(OCO)] dimeric units. The diperiodic layer motifs stack in an pattern mediated by C-H⋯O supra-molecular inter-actions between ada ligands and water mol-ecules of crystallization to form the full triperiodic crystal structure of the title compound.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626845PMC
http://dx.doi.org/10.1107/S2414314623008696DOI Listing

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