Cu(I)-Hydrido complexes supported by dibenzo[]azepinyl -alkene hybrid ligands and stabilized by electrostatic interactions in a Cu-H⋯KCl⋯BR arrangement can be trapped with CO at low temperature to afford Cu(I)-formates. The complexes are isolable with and without a pendant BEt group and show strong Cu-O and weak B-O interactions.
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| http://dx.doi.org/10.1039/d3cc03033d | DOI Listing |
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