Herein, a diode laser-assisted micro-pyrolysis (LAMP) technique coupled with FAPA high resolution mass spectrometry (HRMS) is demonstrated for fast chemical characterization of lignocellulosic biomass feedstocks. The solid lignocellulosic biomass can be analyzed directly with minimal sample preparation. The mass spectra of the pyrolysis products are interpreted with the aid of data visualization tools such as Kendrick mass defect (KMD) plots and van Krevelen plots. Furthermore, quantitation of lignin/cellulose/hemicellulose, sugar contents of glucan/xylan/galactan/arabinan and lignin monomeric unit S/G is achieved with good accuracy and precision, through multivariate analysis methods, including partial least squares regression (PLSR) and support vector regression (SVR).
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| http://dx.doi.org/10.1016/j.talanta.2023.125333 | DOI Listing |
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Article Synopsis
- Lignin nanoparticles (LNPs) are being recognized for their eco-friendly properties and potential in sustainable materials.
- A new two-step fractionation technique has created four lignin fractions (F1, F2, F3, and F4) with optimal characteristics for LNPs production, achieving a high recovery rate of 88.7% from alkali lignin.
- The study highlights how the size and structural properties of LNPs can be controlled for better antibacterial and antioxidant performance, particularly favoring a higher syringyl/guaiacyl ratio for smaller nanoparticles.
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