Water vapour induced structural flexibility in a square lattice coordination network.

Chem Commun (Camb)

Bernal Institute, Department of Chemical Sciences, University of Limerick, Limerick V94 T9PX, Republic of Ireland.

Published: November 2023

Herein, we introduce a new square lattice topology coordination network, sql-(1,3-bib)(ndc)-Ni, with three types of connection and detail its gas and vapour induced phase transformations. Exposure to humidity resulted in an S-shaped isotherm profile, suggesting potential utility of such materials as desiccants.

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Source
http://dx.doi.org/10.1039/d3cc04109cDOI Listing

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