The nonclassicality of quantum states is a fundamental resource for quantum technologies and quantum information tasks, in general. In particular, a pivotal aspect of quantum states lies in their coherence properties, encoded in the nondiagonal terms of their density matrix in the Fock-state bosonic basis. We present operational criteria to detect the nonclassicality of individual quantum coherences that use only data obtainable in experimentally realistic scenarios. We analyze and compare the robustness of the nonclassical coherence aspects when the states pass through lossy and noisy channels. The criteria can be immediately applied to experiments with light, atoms, solid-state system, and mechanical oscillators, thus providing a toolbox allowing practical experiments to more easily detect the nonclassicality of generated states.
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http://dx.doi.org/10.1103/PhysRevLett.131.160201 | DOI Listing |
Nanoscale
January 2025
Department of Chemistry, Maulana Azad National Institute of Technology, Bhopal-462003, India.
Mixing different metal ions at the B site of ABX perovskites offers a promising approach for addressing challenges related to toxicity, stability and performance in optoelectronic applications. One such example is CsPbSnBr which addresses the toxicity issue posed by lead while allowing us to tune optoelectronic properties such as the band gap. In this work, nearly monodisperse CsPbSnBr quantum dots (QDs) were synthesized with variable Pb/Sn compositions, CsPbBr, CsPbSnBr and CsPbSnBr.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, U.K.
Using many-body perturbation theory, we study the optical properties of phenylthiolate-capped cadmium sulfide nanoparticles to understand the origin of the experimentally observed blue shift in those properties with decreasing particle size. We show that the absorption spectra predicted by many-body perturbation theory agree well with the experimentally measured spectra. The results of our calculations demonstrate that all low-energy excited states correspond to a mixture of two fundamental types of excitations: intraligand and ligand-to-metal charge-transfer excitations.
View Article and Find Full Text PDFACS Biomater Sci Eng
January 2025
Environment Emission and CRM Section, CSIR-Central Institute of Mining and Fuel Research Dhanbad, Jharkhand, 828108, India.
Carbohydrate-functionalized quantum dots exhibit excellent physical characteristics and enhance the steric interaction with biological cells and tissues. Glycoconjugation of quantum dots promotes aqueous solubility, stability, and reduced immunogenicity. Carbohydrate-protein interactions are involved in various vital processes and provide insight into cellular recognition, cell-to-cell communication, pathogenicity, antigen-antibody recognition, and enzymatic action.
View Article and Find Full Text PDFJ Chem Inf Model
January 2025
Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States.
Gold nanoparticles can exhibit unique physical and chemical properties, such as plasmon resonances or photoluminescence. These nanoparticles have many atoms, which leads to high computational costs for density functional theory (DFT) calculations. In this work, we used the FLARE++ (fast learning of atomistic rare events) code and incorporated an active learning algorithm to construct force fields for gold thiolate-protected nanoclusters.
View Article and Find Full Text PDFThe intrinsic spontaneous and piezoelectric polarizations of GaN lead to the formation of triangular wells and barriers, resulting in the manifestation of chaotic transport models in GaN quantum well intersubband transition (ISBT) infrared detectors and giving rise to various adverse effects. The APSYS software was utilized to construct a novel GaN quantum well ISBT infrared detector in this study. By endeavoring to modify the quantum well structure, our objective was to precisely adjust the energy level of the first excited state (E1) to align with the apex of the triangular barrier.
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