Xylan derived fluorescence carbon dots composite with cotton cellulose paper as 'turn-off' fluorescence platform for sensitive and selective detection Cu in real samples.

Int J Biol Macromol

Joint Laboratory of Advanced Biomedical Materials (NFU-UGent), Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University (NFU), Nanjing 210037, China. Electronic address:

Published: January 2024

The pollution of heavy metals such as Cu is still serious and the discharge of sewage of Cu will cause damage to soil environment and human health. Herein, a biomass-based solid-state fluorescence detection platform (CPU-CDs) was developed as fluorescent sensor for detection Cu via fluorescence and colorimetric dual-model methods in real time. CPU-CDs was composed of xylan-derived CDs (U-CDs) and cotton cellulose paper, which exhibiting good reusability, non-toxicity, excellent fluorescence characteristics and high biocompatibility. Further, CPU-CDs displayed high effectiveness and sensitivity for Cu with the detection limit as low as 0.14 μM, which was well below U.S. EPA safety levels (20 μM). Practical application indicated that CPU-CDs could achieve precision response of Cu change in real environment water samples with good recovery range of 90 %-119 %. This strategy demonstrated a promising biomass solid-state fluorescence sensor for Cu detection for water treatment research, which is of great significance in dealing with water pollution caused by heavy metal ions.

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http://dx.doi.org/10.1016/j.ijbiomac.2023.127707DOI Listing

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