AI Article Synopsis
- The research focuses on creating efficient mixed matrix membranes (MMMs) using metal-organic frameworks (MOFs) that are uniformly dispersed and highly loaded, addressing key challenges in their application.
- A new method is introduced to synthesize oriented CuBDC/poly(m-phenylenediamine) (CuBDC/PmPD) MMMs at the air-solution interface, utilizing the dual function of metal ions for even MOF distribution.
- The resulting MMM demonstrates strong separation capabilities for ion sieving and seawater desalination, thanks to its structural integrity and interconnected channels formed by the oriented MOF distribution, paving the way for advanced membrane technologies.
Article Abstract
Developing a facile strategy for constructing oriented mixed matrix membranes (MMMs) with uniformly dispersed and high-loading metal-organic frameworks (MOFs) is a crucial scientific challenge in probing the enhanced capability and potential applications of MOF-polymer MMMs. Herein, a novel synchronous synthetic method for constructing oriented CuBDC/poly(m-phenylenediamine) (CuBDC/PmPD) MMM with uniform MOF dispersion at high loading at the air-solution interface via the dual function of metal ions is reported. The resulting MMM exhibits excellent separation performance in ion sieving and seawater desalination due to the structural integrity of the proposed membrane and the highly interconnected channels created through the oriented distribution of MOF in a polymer matrix. Such a cutting-edge approach may provide promising insights into the development of advanced MMMs with optimized structure and superior performances.
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| http://dx.doi.org/10.1002/smll.202305688 | DOI Listing |
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