Laser frequency combs are enabling some of the most exciting scientific endeavours in the twenty-first century, ranging from the development of optical clocks to the calibration of the astronomical spectrographs used for discovering Earth-like exoplanets. Dissipative Kerr solitons generated in microresonators currently offer the prospect of attaining frequency combs in miniaturized systems by capitalizing on advances in photonic integration. Most of the applications based on soliton microcombs rely on tuning a continuous-wave laser into a longitudinal mode of a microresonator engineered to display anomalous dispersion. In this configuration, however, nonlinear physics precludes one from attaining dissipative Kerr solitons with high power conversion efficiency, with typical comb powers amounting to ~1% of the available laser power. Here we demonstrate that this fundamental limitation can be overcome by inducing a controllable frequency shift to a selected cavity resonance. Experimentally, we realize this shift using two linearly coupled anomalous-dispersion microresonators, resulting in a coherent dissipative Kerr soliton with a conversion efficiency exceeding 50% and excellent line spacing stability. We describe the soliton dynamics in this configuration and find vastly modified characteristics. By optimizing the microcomb power available on-chip, these results facilitate the practical implementation of a scalable integrated photonic architecture for energy-efficient applications.
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http://dx.doi.org/10.1038/s41566-023-01280-3 | DOI Listing |
ACS Nano
January 2025
Key Laboratory of Mesoscopic Chemistry of MOE and Jiangsu Provincial Laboratory of Nanotechnology, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.
Ammonia synthesis via nitrate electroreduction is more attractive and sustainable than the energy-extensive Haber-Bosch process and intrinsically sluggish nitrogen electroreduction. Herein, we have designed a single-site Cu catalyst on hierarchical nitrogen-doped carbon nanocage support (Cu/hNCNC) for nitrate electroreduction, which achieves an ultrahigh ammonia yield rate (YR) of 99.4 mol h g (2.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Inner Mongolia University, College of Chemistry and Chemical Engineering, Hohhot 010021, P. R. China., 010021, Hohhot, CHINA.
Conversion of solar energy into value-added chemicals through photoelectrochemistry (PEC) holds great potential for advancing sustainable development but limits by high onset potential which affects energy conversion efficiencies. Herein, we utilized a CuPd cocatalyst-modified Sb2(S,Se)3 photocathode (CuPd/TSSS) to achieve an ultra-low onset potential of 0.83 VRHE for photoelectrochemical ammonia synthesis.
View Article and Find Full Text PDFCell Biosci
January 2025
Department of Infectious Diseases, Tangdu Hospital, Air Force Medical University, Xi'an, 710038, China.
Background: Japanese encephalitis (JE) induced by Japanese encephalitis virus (JEV) infection is the most prevalent diagnosed epidemic viral encephalitis globally. The underlying pathological mechanisms remain largely unknown. Given that viruses are obligate intracellular parasites, cellular metabolic reprogramming triggered by viral infection is intricately related to the establishment of infection and progression of disease.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China.
Organic solar cells have seen significant progress in the past 2 decades with power conversion efficiencies (PCEs) exceeding 20% but mostly based on high-cost photovoltaic materials. Polythiophenes (PTs) without a fused-ring structure are good candidates as low-cost donor materials, deserving more attention for studying. In this work, ester-substituted thiazole (E-Tz) was explored as the electron-withdrawing unit to design PTs, and further optimization on the fluorinated/nonfluorinated donor segment contents via copolymerization strategy was simultaneously performed, yielding polymer donors of PTETz-100F, PTETz-80F, and PTETz-0F.
View Article and Find Full Text PDFNat Commun
January 2025
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, 610065 Chengdu, China.
Dual-atom catalysts featuring synergetic dinuclear active sites, have the potential of breaking the linear scaling relationship of the well-established single-atom catalysts for oxygen reduction reaction; however, the design of dual-atom catalysts with rationalized local microenvironment for high activity and selectivity remains a great challenge. Here we design a bisalphen ladder polymer with well-defined densely populated binuclear cobalt sites on Ketjenblack substrates. The strong electron coupling effect between the fully-conjugated ladder structure and carbon substrates enhances the electron transfer between the cobalt center and oxygen intermediates, inducing the low-to-high spin transition for the 3d electron of Co(II).
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