The evolution of a foam driven by the transfer of two gases of different solubilities across the soap films is studied. A bamboo foam, or a train of films, is used as a model system; it is made of a poorly soluble gas and put into contact with a reservoir of a soluble gas at an initial time. The measurement of the time evolution of the volume of each bubble shows that the foam swells as it progressively incorporates the soluble gas. The dynamics is modeled from the gas fluxes across each film. The continuous limit of this model at a large number of bubbles is studied in detail: it gives an effective nonlinear diffusion equation, which fits the data very well. The corresponding diffusion constant, given by the product of the permeability of the soluble gas and the initial size of the bubbles, is shown to be the key parameter governing the coarsening dynamics of the foam.
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http://dx.doi.org/10.1021/acs.langmuir.3c02533 | DOI Listing |
J Environ Manage
January 2025
Laboratório de Plasmas e Processos - LPP, Instituto Tecnológico de Aeronáutica - ITA/DCTA, São José dos Campos, SP, Brazil.
This study aimed to investigate the thermal plasma treatment of sewage sludge as an alternative waste management solution. Samples were collected from a sewage treatment facility in São Paulo, Brazil, and subjected to thermal treatments in a furnace at temperatures of 400, 600, 800, and 900 °C to assess moisture content, mass loss, and ash composition. Subsequently, the samples were processed in a thermal plasma reactor operating at an average power of 30 kW.
View Article and Find Full Text PDFPlant Physiol Biochem
January 2025
Department of Environmental Sciences, Government College University Allama Iqbal Road, Faisalabad 38000, Pakistan; Department of Biological Sciences and Technology, China Medical University, Taichung, 40402, Taiwan. Electronic address:
Soil contamination with toxic heavy metals [such as cadmium (Cd)] is becoming a serious global problem due to the rapid development of the social economy. Organic chelating agents such as succinic acid (SA) and oxalic acid (OA) are more efficient, environmentally friendly, and biodegradable compared to inorganic chelating agents and they enhance the solubility, absorption, and stability of metals. To investigate this, we conducted a pot experiment to assess the impact of SA (0.
View Article and Find Full Text PDFJ Contam Hydrol
January 2025
BCEG Environmental Remediation Co., Ltd., Beijing 100015, China; National Engineering Laboratory for Site Remediation Technologies, Beijing 100015, China.
The dissolution of polycyclic aromatic hydrocarbons (PAHs) from coal tar at former manufactured gas plant (FMGP) sites is a long-term threat to groundwater quality. The dissolution rate is often limited by an increase in the viscosity of the non-aqueous phase liquid (NAPL) as the lower molecular weight compounds are depleted over time, and this slow mass transfer prevents the effective application of remediation technologies that rely on NAPL-to-water mass transfer to remove or degrade mass. Increasing subsurface temperatures has the potential to increase mass transfer at FMGP sites by increasing PAH solubility and reducing NAPL viscosity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China.
Polyimide (PI)-based gas separation membranes are of great interest in the field of H purification owing to their good thermal stability, chemical stability, and mechanical properties. Among polyimide-based membranes, intrinsically microporous polyimides are easily soluble in common organic solvents, showing great potential for fabricating hollow fiber gas separation membranes. However, based on the solution-diffusion model, improving the free volume or the movability of polymer chains can improve gas permeability, but would result in poor thermal stability.
View Article and Find Full Text PDFAnesthesiology
January 2025
Department of Critical Care, Melbourne Medicine School, Faculty of Medicine, Dentistry and Health Sciences, University of Melbourne, Victoria, Australia.
Background: Multi-compartment computer models of heterogeneity in alveolar ventilation-perfusion ratios (VA/Q scatter) across the lung explain the significant alveolar-arterial (A-a) partial pressure gradients and associated alveolar dead-space fractions (VDA/VA) seen in anesthetized patients for both carbon dioxide and for anesthetic gases of different blood solubilities. However, the accuracy of a simpler two-compartment model of VA/Q scatter to do this has not been tested or compared to calculations from the traditional Riley model with "ideal", unventilated (shunt) and unperfused (deadspace) compartments.
Methods: Measurements of gas partial pressures in inspired and expired gas and arterial and mixed venous blood from 29 patients undergoing inhalational general anesthesia for cardiac surgery was used to compare the accuracy of two simple models of VA/Q scatter and lung gas exchange in predicting measured alveolar and arterial partial pressure differences, and associated alveolar dead-space calculations for the modern anesthetic gases isoflurane, sevoflurane and desflurane.
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