AI Article Synopsis
- The oxidation of 10,15-diaryl-21-carba-23-selenaporphyrinoids leads to the formation of dyads through a dimerization process.
- The reaction follows a [5+2] cycloaddition mechanism, creating an azepine unit as part of the structure.
- The resulting compounds have a distinctive open seashell-like shape, with two carbaporphyrinoid planes arranged at an angle due to bonds formed between their carbon and nitrogen atoms.
Article Abstract
The oxidation of 10,15-diaryl-21-carba-23-selenaporphyrinoids resulted in the creation of dyads. The dimerization process follows a [5+2] cycloaddition path with the formation of an azepine unit. The arrays display two direct bonds between the peripheral carbocyclic carbon atoms of one carbaselenaporphyrinic subunit and the central carbon and nitrogen atoms of the second subunit. This results in a unique canted arrangement of two carbaporphyrinoid planes resembling an open seashell-like motif.
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| http://dx.doi.org/10.1002/anie.202314925 | DOI Listing |
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