Boosting Carbon Dioxide Reduction in a Photocatalytic Fuel Cell with a Bubbling Fluidized Cathode: Dual Function of Titanium Carbide.

Photoelectrochemical reduction of carbon dioxide (CO) is a promising avenue to realize resourceful utilization of carbon dioxide and mitigate the energy shortage. Herein, a photocatalytic fuel cell with a bubbling fluidized cathode (PFC-BFC) is proposed to increase the performance of the photocatalytic CO reduction reaction (CORR). Titanium carbide (TiC) is first used as a fluidized cathode catalyst with the dual features of superior capacitance and high CORR catalytic activity. Compared with the conventional PFC system, the as-proposed PFC-BFC system exhibits a higher gas production performance. Particularly, the generation rate and Faraday efficiency for CH production reach to 37.2 μmol g h and 72%, which are 10.9 and 6.5 times higher than that of the conventional PFC system, respectively. The bubbling fluidized cathode allows a rapid electron transfer between catalysts and the current collector and an efficient diffusion of catalysts in the whole solution, thus remarkably increasing the effective reaction area of the CORR. In addition, the fluidized reaction mechanism of charging/discharging-coupled CORR is investigated. Significantly, a magnified PFC-BFC system is designed and exhibits a similar gas generation rate compared to that of the small-scale system, indicating a good potential of scaling up in the industry applications. These results demonstrated that the proposed PFC-BFC system can maximize the utilization of catalyst active sites and enhance the reaction kinetics, providing an alternative design for the application of CORR.