-Butylhydroquinone (TBHQ) is a novel synthetic antioxidant with a higher safety profile and antioxidant effect that is more excellent than other synthetic antioxidants and is internationally recognized as one of the best food antioxidants. However, its excessive use in food can have unfavorable effects on the human body. Thus, it is critical to establish a rapid method for the detection of TBHQ in food samples. In this study, a cobalt-based metal-organic framework (Co-MOF) was fabricated by a one-pot hydrothermal method and embedded in multi-walled carbon nanotubes (MWCNTs) to construct an economical and sensitive electrochemical sensor for TBHQ. The results showed that this sensor possessed a wide linear range (0.004-20 μM and 20-300 μM), a low limit of detection (LOD = 2.5 nM, S/N = 3) as well as an ultra-high sensitivity (43.19 μA μM cm). Moreover, the sensor also has superior selectivity, repeatability, reproducibility and anti-interference ability and can be successfully applied for the detection of TBHQ in samples of instant noodles and potato chips.
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http://dx.doi.org/10.1039/d3dt03158f | DOI Listing |
Food Chem
December 2024
International Ph.D. Program in Innovative Technology of Biomedical Engineering and Medical Devices, Ming Chi University of Technology, New Taipei City 243303, Taiwan; Research Center for Intelligence Medical Devices, Ming Chi University of Technology, New Taipei City 243303, Taiwan; Centre for Applied Research, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Chennai 602105, Tamil Nadu, India. Electronic address:
In modern life, people often neglect to consider their eating habits. Antioxidants are primarily used as food additives due to their stability and low toxicity. TBHQ is a commonly used antioxidant in food products as an additive.
View Article and Find Full Text PDFFood Chem
February 2025
School of Health and Life Sciences, Teesside University, Middlesbrough, UK.
This study investigates the integration of Broadband Cavity Enhanced Absorption Spectroscopy (BBCEAS) with High-Performance Liquid Chromatography (HPLC) to detect synthetic antioxidants; BHA, BHT, and TBHQ in the deep-UV region below 300 nm. The research addresses the need for more sensitive and cost-effective detection methods in HPLC systems, particularly for low analyte concentrations, by exploring BBCEAS as a superior alternative to conventional detectors that often fall short in sensitivity. The sensitivity of the HPLC-BBCEAS system is assessed by calculating the minimum detectable change in the absorption coefficient (αmin) and comparing with those obtained using conventional HPLC and single-wavelength HPLC-CRDS methods.
View Article and Find Full Text PDFFoods
October 2024
School of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, China.
Food Chem
February 2025
Department of Chemistry, Panjab University Chandigarh, 160014, India. Electronic address:
The demand for processed foods relies heavily on synthetic antioxidants like TBHQ and BHA to prevent spoilage. However, their excessive use poses health risks, prompting regulatory measures in many countries to ensure food safety. In this concern, a proficient electrochemical sensor for the simultaneous detection of tert-butylhydroquinone (TBHQ) and butylated hydroxyanisole (BHA) was designed.
View Article and Find Full Text PDFFood Chem
January 2025
Department of Chemistry, Stella Maris College, Affiliated to the University of Madras, Chennai, Tamil Nadu 600086, India.. Electronic address:
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