A large volume of polymeric waste is generated in cities, and some of this reaches the sea and beaches. This waste stays for hundreds of years, damaging marine environments and organisms. To minimize the effects of pollution, collection and recycling allow a return to the production chain. This research aims to produce and evaluate a polymeric mixture obtained via processing plastic waste collected on the beaches of the city of Ilhéus-Bahia. Subsequently, the mixture is converted into a granulated form for application as fine aggregate in the production of cementitious matrices. A polymer blend of polystyrene, polypropylene, and high- and low-density polyethylene was obtained and evaluated by thermal, morphological, and mechanical tests in three processing stages. The degradation temperatures were close for the three processing stages and the level of processing influenced the mechanical strength. As for elastic modulus and deformation, there was no significant difference in using the mixture processed once or twice. The results showed that the reuse of the waste is applicable, the mixture presented a compact, reasonably homogeneous material with different morphology. Therefore, this work finds importance in the possibility of promoting waste recycling and adding value to a material that would become waste, thus showing its potential for application in the construction industry as an addition to cementitious mixtures and leading to savings in inputs.
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http://dx.doi.org/10.3390/polym15204155 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Hydrogen and Renewable Energy, Kyungpook National University, Daegu 41566, Republic of Korea.
The side-chain directions in nonfullerene acceptors (NFAs) strongly influence the intermolecular interactions in NFAs; however, the influence of these side chains on the morphologies and charge carrier dynamics of Y6-based acceptors remains underexplored. In this study, we synthesize four distinct Y6-based acceptors, i.e.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China.
Asymmetric substitution is acknowledged as a straightforward yet potent approach for the optimization of small molecule acceptors (SMAs), thereby enhancing the power conversion efficiency (PCE) of organic solar cells (OSCs). In this work, we have successfully engineered and synthesized a novel asymmetric SMA, designated as Y6-R, which features a rhodanine-terminated inner side-chain. In devices with PM6 as the polymer donor, the asymmetric Y6-R demonstrated an impressive PCE of 18.
View Article and Find Full Text PDFScientificWorldJournal
January 2025
Department of Biochemistry and Biotechnology, College of Science, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana.
Bioethanol production is one of the key alternatives for fossil fuel use due to climate change. The study seeks to upscale tailor-made onsite enzyme blends for the bioconversion of cassava peels to bioethanol in simultaneous saccharification and fermentation (SSF) process using cassava peels-degrading fungi. The starch and cellulose contents of peels were determined.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Food Science and Technology, Sari Agricultural Science and Natural Resources University, PO BOX 578, Sari, Mazandaran, Iran.
This study aimed to develop bead-free nanofibers for effective omega-3 encapsulation using optimal mixing ratios of whey protein isolate (WPI)/polyvinyl alcohol (PVA) blends via electrospinning method. Various WPI-PVA ratios (100:0, 90:10, 80:20, 70:30, 60:40, 50:50 v/v) were examined for surface tension, viscosity, and conductivity. SEM images revealed uneven nanofibers with bead at 90:10 and 80:20 ratios, while the 70:30 ratio produced uniform and bead-free nanofibers with an average diameter of 262.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia.
This study focuses on the development of an efficient membrane-based clarification process to enhance the performance of subsequent ultrafiltration and produce high-quality sweet lime juice. A range of casting solutions were prepared using a blend of pore-forming polymers, including polyvinylpyrrolidone (PVP), polyvinylidene fluoride (PVDF), and cellulose acetate (CA), dissolved in dimethylformamide (DMF) solvent through the phase inversion technique. To further enhance the membrane's performance, four biopolymers poly (lactic acid) (PLA), xanthan gum, chitosan, and gelatin were incorporated, with and without clay, to refine its structure, porosity, and surface properties.
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