In this study, we investigated the influence of BiO and WO on both structure and optical properties of 50ZnO:(49 - x)BO:1BiO:xWO; x = 1, 5, 10 glasses doped with 0.5 mol% EuO. IR spectroscopy revealed the presence of trigonal BØ units connecting superstructural groups, [BØO] metaborate groups, tetrahedral BØ units in superstructural groupings (Ø = bridging oxygen atom), borate triangles with nonbridging oxygen atoms, [WO] tetrahedral, and octahedral WO species. Neutron diffraction experimental data were simulated by reverse Monte Carlo modeling. The atomic distances and coordination numbers were established, confirming the short-range order found by IR spectra. The synthesized glasses were characterized by red emission at 612 nm. All findings suggest that Eu doped zinc borate glasses containing both WO and BiO have the potential to serve as a substitute for red phosphor with high color purity.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10608091PMC
http://dx.doi.org/10.3390/ma16206779DOI Listing

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