The formulation of magnetic ionic liquids (MILs) or organic salts based on lanthanides as anions has been explored. In this work, a set of choline-family-based salts, and two other, different cation families, were combined with Gadolinium(III) and Terbium(III) anions. Synthetic methodologies were previously optimized, and all organic salts were obtained as solids with melting temperatures higher than 100 °C. The magnetic moments obtained for the Gd(III) salts were, as expected, smaller than those obtained for the Tb(III)-based compounds. The values for Gd(III) and Tb(III) magnetic salts are in the range of 6.55-7.30 MB and 8.22-9.34 MB, respectively. It is important to note a correlation between the magnetic moments obtained for lanthanides, and the structural features of the cation. The cytotoxicity of lanthanide-based salts was also evaluated using 3T3, 293T, Caco2, and HepG2 cells, and it was revealed that most of the prepared compounds are not toxic.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10608950 | PMC |
| http://dx.doi.org/10.3390/molecules28207152 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Dinitramide salts based on nitropyrazole-diaminotriazole hybrid: novel ionic energetic materials with high-energy and low-sensitivity.
Phys Chem Chem Phys
January 2025
Experimental Center of Advanced Materials, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
In this study, employing a simple anion exchange strategy and straightforward three-step synthetic route, a pair of promising nitrogen-rich heterocyclic cation and oxygen-rich anion were assembled together to generate two novel dinitramide energetic salts, both of which exhibit prominent detonation performance comparable to benchmark explosive RDX while possessing significantly lower mechanical sensitivity than RDX, thereby highlighting them as promising candidates for advanced secondary explosives. This work has directly led to a practical protocol for the design of chloride-free environmentally friendly IEMs, and accelerates the development of organic explosives with high-energy and low-sensitivity.
View Article and Find Full Text PDFMerging halogen atom transfer, ring-expansion and oxidation by electron-rich arenediazonium salts: modular assembly of cyclohexenone derivatives.
Chem Commun (Camb)
January 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Siwangting Road 180, 225002, Yangzhou, China.
As fundamental structural scaffolds in numerous natural products and pharmaceutical molecules, the construction of cyclohexenone architectures has remained a pivotal focus in organic chemistry. However, established strategies to synthesize cyclohexenone derivatives Dowd-Beckwith ring-expansion reaction invariably involve the use of transition metals and photoirradiation. Herein, we present a novel transition-metal- and photoirradiation-free pathway to access such structures from α-iodomethyl β-keto esters with electron-rich arenediazonium salts as inexpensive radical initiators and oxidants under mild reaction conditions.
View Article and Find Full Text PDFMolecular junctions (MJs) are celebrated nanoelectronic devices for mimicking conventional electronic functions, including rectifiers, sensors, wires, switches, transistors, negative differential resistance, and memory, following an understanding of charge transport mechanisms. However, capacitive nanoscale molecular junctions are rarely seen. The present work describes electrochemically (E-Chem) grown covalently attached molecular thin films of 10, 14.
View Article and Find Full Text PDFEvaluation of a new technology for terminal sterilization of flexible endoscopes using hydrogen peroxide gas plasma.
Infect Control Hosp Epidemiol
January 2025
Research Service, VA Northeast Ohio Healthcare System, Cleveland, OH, USA.
In laboratory testing, a novel hydrogen peroxide gas plasma endoscope sterilizer consistently reduced vegetative organisms, but not bacterial spores, to undetectable levels in the presence of high organism load (≥6.5 log) and organic material and salts. These findings highlight the importance of meticulous cleaning of endoscopes prior to sterilization.
View Article and Find Full Text PDFNitrogen removal from multi-electrolyte saline wastewater via mainstream anammox in warm climate conditions.
J Environ Manage
January 2025
Biological Processes Laboratory (LPB), São Carlos School of Engineering (EESC), University of São Paulo (USP), Av. João Dagnone, 1100, Santa Angelina, São Carlos, São Paulo, 13563-120, Brazil.
High salts concentrations in wastewater hinder its biological treatment. Recent research has investigated the inhibitory effect of salinity on the anammox process, mainly focusing on NaCl. Thus, the inhibition caused by multi-electrolytes salinity on freshwater anammox bacteria remains unclear.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!