This paper focuses on preparing broadband reflective liquid crystal films through the diffusion of monofunctional and bifunctional monomers in a photoinduced trilayer system. By combining the hydrophilic and hydrophobic liquid crystal glass surface treatment technologies, the polymer network of polymer-stabilized cholesteric liquid crystal (PSCLC) itself serves as a diffusion channel to form a trilayer cholesteric liquid crystal composite system containing bifunctional monomers, a nematic liquid crystal composite system, and a cholesteric liquid crystal composite system containing monofunctional monomers. Utilizing the difference in the polymerization rates of monofunctional and difunctional polymerizable monomers, the monomers and chiral compounds diffuse relative to each other, so that the liquid crystal pitch exhibits a gradient distribution, and the broadened reflective width can reach up to 1570 nm. There is no doubt that new and improved processes and technologies offer important possibilities for preparing and applying PSCLC films.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609433PMC
http://dx.doi.org/10.3390/molecules28207063DOI Listing

Publication Analysis

Top Keywords

liquid crystal
32
cholesteric liquid
16
crystal composite
12
composite system
12
liquid
8
crystal
8
bifunctional monomers
8
monomers
5
multilayer broadband
4
broadband infrared
4

Similar Publications

Liquid crystal elastomers (LCEs) with various deformation properties based on phase transition were widely used as actuators and provided potential to fabricate functional surfaces with tunable microstructure. Herein, we demonstrate a strategy to fabricate dynamic micro wrinkles on LCE surfaces based on LC phase transition. Stable micron-sized surface wrinkles on the anthracene-containing LCE film (AnLCE) are fabricated by ultraviolet exposure induced gradient cross-linking and subsequently stretching-releasing (UV-SR).

View Article and Find Full Text PDF

A liquid crystal elastomer (LCE) actuator capable of colorimetric humidity sensing is realized. The designed LCE features acid protonated amino azobenzene side groups in its structure, which endow the actuator with the hygroscopicity and act as the humidity reporter via color changes. Given that the protonated and deprotonated chromophore absorb visible light at different wavelengths, when the protonated LCE is under higher humidity, it absorbs more water that deprotonates azobenzene and leads to a change in color.

View Article and Find Full Text PDF

Structural Color Contact Lenses from Cholesteric Cellulose Liquid Crystals.

Small Methods

December 2024

Institute of Translational Medicine, Nanjing Drum Tower Hospital, School of Biological Science and Medical Engineering, Southeast University, Nanjing, 210096, China.

Colored contact lenses have gained popularity among young individuals owing to their ability to alter the appearance of the wearer's eyes. However, conventional lenses containing chemical dyes are susceptible to detachment of the pigment layer, which can lead to corneal damage. In this research, a novel cellulose-based structural color contact lens (SCCL) is presented that enhances aesthetic appeal via a cholesteric liquid crystal (CLC) layer.

View Article and Find Full Text PDF

Introduction: The persistence of in the contaminated environment is sustained by tolerance to biocides and ability to growth as biofilm. The aim of the study was to analyze the susceptibility of biofilms to chlorhexidine (CHX) and benzalkonium (BZK) biocides and the ability of natural monomeric stilbenoid resveratrol (RV) to modulate the phenomenon.

Methods: Biofilm formation and preformed biofilm were tested by Crystal violet and tetrazolium salt reduction assay, respectively.

View Article and Find Full Text PDF

Maintaining hexagonal structures through interfacial positioning of crosslinkers for nanofiltration.

J Colloid Interface Sci

December 2024

Institute for Frontier Materials, Deakin University, Geelong VIC 3216, Australia. Electronic address:

Hypothesis: Optimizing interfacial positioning of crosslinkers within a reactive self-assembled hexagonal lyotropic liquid crystals (HLLC) system could assist in retaining the hexagonal structure during polymerization and thereby improving water filtration performances of the as-synthesized nanofiltration membranes.

Experiments: The positioning of the hydrophilic crosslinker, poly (ethylene glycol) diacrylate (PEGDA), within the reactive HLLC system was systematically investigated using H and C solid nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. The structural variation and water filtration performances of these HLLC systems with/without crosslinkers after polymerization were further studied using grazing incidence SAXS (GISAXS) and crossflow filtration tests, respectively.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!