This study presents an exergetic analysis of xylitol fermentative production from hemicellulose hydrolysate, aiming to optimize operational conditions in a fluidized bed bioreactor. The aerobic fermentation conditions evaluated in this study (gas flow rate - x, hydrolysate concentration factor - x, and recirculation flow rate - x) were optimized using various exergetic parameters and xylitol yield as objective functions. Four objective functions were defined for the mono-objective optimization process: rational exergetic efficiency, normalized destroyed exergy, thermodynamic sustainability index, and xylitol yield factor. The results reveal that the optimization problem involves conflicting objectives when considering both yield-based and exergy-based approaches. Thus, the bioreactor's performance was formulated as a multi-objective problem, where the yield factor and thermodynamic sustainability index were simultaneously maximized. For the multi-objective optimization, the ideal operational variable ranges were found to be: 594 ≤x≤ 619 mL/min, x= 7 e 37 ≤x≤ 57 L/h.
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http://dx.doi.org/10.1016/j.biortech.2023.129910 | DOI Listing |
ACS Omega
December 2024
Department of Chemical Engineering, KU Leuven, 3001 Leuven, Belgium.
Residual biomass is a promising carbon feedstock for the production of electricity-based organic chemicals and fuels since, unlike carbon dioxide captured from point sources or air, it also has a valuable energy input. Biomass can be converted into an intermediate stream suitable for Power-to-X processes mainly via combustion or gasification. Such combined processes are generally called biohybrid or Power- and Biomass-to-X processes.
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November 2024
Department of Refrigeration and Air Conditioning Technology, Faculty of Technology and Education, Helwan University, 11282, Cairo, Egypt.
In the present investigation, the exergy of an innovative technique involving the integration of curved helical tubes with twisted passages was experimentally presented. This technique aims to improve the thermofluid characteristics by involving the swirl intensity of fluid flow in a twisted tube helical coil (TTHC). Six identical geometries with different pitch ratios Υ of 36 mm, 54 mm, and ∞ (smooth/no twisted) were experimentally explored at two different inner tube profiles of triangular and square cross-sections in counter flow arrangements.
View Article and Find Full Text PDFEntropy (Basel)
October 2024
Institute for Energy Engineering, Technische Universität Berlin, Marchstr. 18, 10587 Berlin, Germany.
Using polygeneration systems is one of the most cost-effective ways for energy efficiency improvement, which secures sustainable energy development and reduces environmental impacts. This paper investigates a polygeneration system powered by low- to medium-grade waste heat and using CO as a working fluid to simultaneously produce electric power, refrigeration, and heating capacities. The system is simulated in Aspen HYSYS and evaluated by applying advanced exergy-based methods.
View Article and Find Full Text PDFEntropy (Basel)
June 2024
Blue Economy Strategy Institute Co., Ltd., #602, 150 Dogok-ro, Gangnam-gu, Seoul 06260, Republic of Korea.
Exergy analysis evaluates the efficiency of system components by quantifying the rate of entropy generation. In general, the exergy destruction rate or irreversibility rate was directly obtained through the exergy balance equation. However, this method cannot determine the origin of the component's entropy generation rate, which is a very important factor in system design and improvement.
View Article and Find Full Text PDFEnergy Fuels
July 2024
Department of Chemical Engineering, Aristotle University of Thessaloniki, University Campus, 54124 Thessaloniki, Greece.
This study investigates a novel concept to coproduce high-purity H and syngas, which couples steam methane reforming with CaO carbonation to capture the generated CO and dry reforming of methane with CaCO calcination to directly utilize the captured CO. The thermodynamic equilibrium of the reactive calcination stage was evaluated using Aspen Plus via a parametric analysis of various operating conditions, including the temperature, pressure, and CH/CaCO molar ratio. Introducing a CH feed in the calcination stage promoted the driving force and completion of CaCO decomposition at lower temperatures (∼700 °C) compared to applying an inert flow, as a result of CO conversion.
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