Large-capacity information encryption has attracted significant interest in the information age. The diversity and controllability of spectra have positioned them to be widely applied for information encryption. Current spectra-based information encryption methods commonly rely on either spectral alteration induced by external stimuli or the utilization of narrowband channels within spectra. However, these methods encounter a common challenge in attaining both high security and large capacity simultaneously. To address these issues, we propose a multiple-channel information encryption system based on quantum dot (QD) absorption spectra. The diversity of QD absorption spectra and their broadband features ensure that the encrypted spectra can hardly be decrypted without knowing the correct channel matrix. Meanwhile, the large capacity is realized through the combination of multiple QD spectral channels with a theoretical maximum capacity of 24.0 bits in a single spectrum. In order to optimize the performance of our proposed system, the selection principle of the channel matrix is established to achieve the rapid identification of the optimal channel matrix in several milliseconds. The additivity of QD spectral channels and the consistency of QD spectra are also explored to minimize the impact of errors on information decryption. Furthermore, two spectral encryption scenarios of spatial pattern and spectral pattern are applied to demonstrate the feasibility, showcasing their ability to achieve both a high level of security and large capacity. Owing to the advantages offered by QD spectra, the QD spectra-based information system exhibits excellent potential for broader applications in information storage, authentication, and computing.
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Anal Methods
November 2017
Centre de Recherche sur la Conservation (CRC), MNHN, Sorbonne-Universités CNRS, MCC, USR 3224, CP21, 36 rue Geoffroy Saint Hilaire, 75005 Paris, France.
Reflectance spectral imaging is a powerful tool for the non-invasive study of cultural heritage objects. Particular visible to short wave infrared (400-2500 nm) spectral features are linked to compositional information. Spectral images can hence be used to generate useful chemical maps.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Environment, Zhejiang University of Technology, Hangzhou, 310014, China.
The generation of radicals through photo-Fenton-like reactions demonstrates significant potential for remediating emerging organic contaminants (EOCs) in complex aqueous environments. However, the excitonic effect, induced by Coulomb interactions between photoexcited electrons and holes, reduces carrier utilization efficiency in these systems. In this study, we develop Cu single-atom-loaded covalent organic frameworks (Cu/COFs) as models to modulate excitonic effects.
View Article and Find Full Text PDFEnviron Int
January 2025
State Key Laboratory of Marine Pollution and Department of Chemistry, City University of Hong Kong, Hong Kong 999077, China; Department of Applied Science, School of Science and Technology, Hong Kong Metropolitan University, Hong Kong 999077, China.
Despite the ubiquity and complexity of atmospheric polycyclic aromatic compounds (PACs), many of these compounds are largely unknown and lack sufficient toxicity data for comprehensive risk assessments. In this study, nontarget screening assisted by in-house and self-developed spectra databases was, therefore, employed to identify PACs in atmospheric particulate matter collected from multiple outdoor settings. Additionally, absorption, distribution, metabolism, excretion, and toxicity properties were evaluated to indicate PAC's overall abilities to cause adverse outcomes and incorporated into a novel health risk assessment model to assess their inhalation risks.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Department of Chemistry, Government College University Faisalabad, Faisalabad 38000 Pakistan; Dry Lab (Janjua.XYZ), Physical Chemistry and Computational Modelling (PCCM), Department of Chemistry, Government College University Faisalabad, Faisalabad 38000 Pakistan. Electronic address:
Organic photovoltaics (OPVs) have improved greatly in recent years in pursuit for efficient and sustainable energy conversion methods. Specifically, utilizing quantum chemistry approaches such as density functional theory (DFT), the electronic structures, energy levels, and charge transport characteristics of donor-π-acceptor (D-π-A) systems based on non-fullerene donor and acceptor molecules have been examined and synthesized. Non-fullerene acceptors offer several advantages over traditional fullerene-based materials, such as enhanced light absorption, modifiable energy levels, and reduced recombination losses.
View Article and Find Full Text PDFPhotosynth Res
January 2025
Graduate School of Life Sciences, Ritsumeikan University, Kusatsu, Shiga, 525-8577, Japan.
Pheophytin-a derivatives possessing plastoquinone and phylloquinone analogs in the peripheral 3-substituent were prepared by Friedel-Crafts reactions of a 3-hydroxymethyl-chlorin as one of the chlorophyll-a derivatives with benzo- and naphthohydroquinones, respectively, and successive oxidation of the 1,4-dihydroxy-aryl groups in the resulting dehydration products. The 3-quinonylmethyl-chlorins exhibited ultraviolet-visible absorption and circular dichroism spectra in acetonitrile, which were composed of those of the starting 3-hydroxymethyl-chlorin and the corresponding methylated benzo- and naphthoquinones. No intramolecular interaction between the chlorin and quinone π-systems was observed in the solution owing to the methylene spacer.
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