Alkali nitridophosphates AP N and A P N (A=Na, K, Rb, Cs) have been known for decades. However, their Li homologues have remained elusive. In this work, the highly condensed lithium (imido)nitridophosphates LiP N and Li P N (NH) (x=1.66(3)) were synthesized from LiPN and P N in the multianvil press at 10 GPa. They constitute the first lithium nitridophosphates with 3D networks exhibiting a degree of condensation larger than 0.5 and high thermal stability. LiP N crystallizes in the orthorhombic space group P2 2 2 with a=4.5846(6) Å, b=8.0094(11) Å, and c=13.252(2) Å (Z=4). Li P N (NH) crystallizes in the triclinic space group P with Z=2, a=4.6911(11) Å, b=7.024(2) Å, c=12.736(3) Å, α=87.726(11), β=80.279(11), and γ=70.551(12)°. Both compounds are stable against hydrolysis in air.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.202303251 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Magnetic vortex: Fundamental physics, developments, and device applications.
J Phys Condens Matter
January 2025
Institute of Engineering & Management, Department of Basic Science and Humanities, Institute of Engineering & Management, Salt Lake Electronics Complex, Sector V, Salt Lake, Kolkata 700091, India, University of Engineering & Management, University Area, Plot No. III, B/5, New Town Road, Action Area III, Newtown, Kolkata 700160, India, Calcutta, West Bengal, 700091, INDIA.
A magnetic vortex (MV) is one of the fundamental and topologically nontrivial spin textures in condensed matter physics. Magnetic vortices are usually the ground states in geometrically restricted ferromagnets with zero magnetocrystalline anisotropy. Magnetic vortices have recently been proposed for use in a variety of spintronics applications due to their resistance to thermal perturbations, flexibility in changing core polarity, simple patterning procedure, and potential uses in magnetic data storage with substantial density, sensors for the magnetic field, devices for logic operations, and other related fields.
View Article and Find Full Text PDFTipping the balance between and ligand conformers in multinuclear ethylzinc cyclophosphazenates.
Dalton Trans
January 2025
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
Hexaanionic cyclophosphazenate ligands [(RN)PN] provide versatile platforms for the assembly of multinuclear metal arrays due to their multiple coordination sites and highly flexible ligand core structure. This work investigates the impact of incrementally increasing the steric demand of the ligand periphery on the coordination behavior of ethylzinc arrays. It shows that the increased congestion around the ligand sites is alleviated by progressive condensation with the elimination of diethylzinc.
View Article and Find Full Text PDFLiZrF-based electrolytes for durable lithium metal batteries.
Nature
January 2025
School of Environment and Energy, State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, South China University of Technology, Guangzhou, China.
Lithium (Li) metal batteries (LMBs) are promising for high-energy-density rechargeable batteries. However, Li dendrites formed by the reaction between highly active Li and non-aqueous electrolytes lead to safety concerns and rapid capacity decay. Developing a reliable solid-electrolyte interphase is critical for realizing high-rate and long-life LMBs, but remains technically challenging.
View Article and Find Full Text PDFEnhancing photocatalytic hydrogen peroxide generation by tuning hydrazone linkage density in covalent organic frameworks.
Nat Commun
January 2025
Department of Chemical and Biological Sciences, S. N. Bose National Centre for Basic Sciences, Kolkata, 700106, India.
The conversion of solar energy into chemical energy or high-value chemicals has attracted considerable research interest in the context of the global energy crisis. Hydrogen peroxide (HO) is a versatile and powerful oxidizing agent widely used in chemical synthesis and medical disinfection. HO also serves as a clean energy source in fuel cells, generating electricity with zero-carbon emissions.
View Article and Find Full Text PDFStereoselective Preparation and Pd-catalyzed Suzuki-Miyaura Cross-coupling of Alkenyl Sulfoximine.
Angew Chem Int Ed Engl
January 2025
Osaka University: Osaka Daigaku, Department of Applied Chemistry, JAPAN.
Although numerous transition-metal catalyzed cross-coupling reactions of alkenyl electrophiles with a sulfur(VI) leaving group, mainly alkenyl sulfones, have been developed, most rely heavily on highly nucleophilic Grignard reagents, and the use of organoboron reagents remains challenging. We report herein facile preparation and the following Pd-catalyzed Suzuki-Miyaura cross-coupling reaction of alkenyl sulfoximine, a monoaza analog of sulfone. The condensation of alkyl sulfoximine with aldehydes, developed in this study, makes alkenyl sulfoximines more readily available.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!