A Doped Lanthanide-Based Coordination Polymer Exhibiting High Relative Sensitivity to Ratiometric Luminescent Thermometers at 440 K.

Inorg Chem

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Published: November 2023

Ratiometric luminescent thermometers with excellent performance often require the luminescent materials to possess high thermal stability and relative sensitivity (). However, such luminescent materials are very rare, especially in physiological (298-323 K) and high-temperature (>373 K) regions. Here we report the synthesis and luminescent property of [TbEu(pfbz)(phen)Cl] (), which not only exhibits high in physiological temperature but also has a up to 7.47% K at 440 K, the largest at 440 K in known lanthanide-based coordination compound luminescent materials.

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http://dx.doi.org/10.1021/acs.inorgchem.3c02225DOI Listing

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