Ratiometric luminescent thermometers with excellent performance often require the luminescent materials to possess high thermal stability and relative sensitivity (). However, such luminescent materials are very rare, especially in physiological (298-323 K) and high-temperature (>373 K) regions. Here we report the synthesis and luminescent property of [TbEu(pfbz)(phen)Cl] (), which not only exhibits high in physiological temperature but also has a up to 7.47% K at 440 K, the largest at 440 K in known lanthanide-based coordination compound luminescent materials.
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http://dx.doi.org/10.1021/acs.inorgchem.3c02225 | DOI Listing |
Inorg Chem
December 2024
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Metal-organic frameworks (MOFs) with long persistent luminescence (LPL) have attracted extensive research attention due to their potential applications in information encryption, anticounterfeiting technology, and security logic. The strategic combinations of organic phosphor linkers and metal ions lead to tremendous frameworks, which could unveil many undiscovered properties of organics. Here, the synthesis and characterization of a three-dimensional MOF (Cd-MOF) is reported, which demonstrates enhanced blue photoluminescence and a phosphorescent lifetime of 124 ms as compared to the pristine linker (HL) under ambient conditions due to the scaffolding and heavy-atom effects of metal chains in the framework.
View Article and Find Full Text PDFFood Chem
December 2024
Laboratory of Functional Polymers, School of Materials Science and Engineering, Linyi University, Linyi 276005, China. Electronic address:
Organicphosphorus is a ubiquitous pesticide that has potential hazards to human health and environmental well-being. Therefore, the precise identification of residues of organophosphorus pesticides (OPs) emerges as an urgent necessity. A ratiometric fluorescent sensor for the detection of OPs by leveraging the catalytic activities of Ce and Ce on the two fluorescent substrates 4-Methylumbelliferyl phosphate (4-MUP) and o-phenylenediamine (OPD) correspondingly was designed.
View Article and Find Full Text PDFBiosensors (Basel)
December 2024
Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering, Chongqing University, No. 174, Shapingba Main Street, Chongqing 400030, China.
In this study, we have proposed an electrochemiluminescence (ECL) signal amplification system which is based on two-dimensional (2D) flower-like CdS@Co/Mo-MOF composites as a co-reaction accelerator of the g-CN/SO system for ultrasensitive detection of chlorpromazine hydrochloride (CPH). Specifically, the 2D flower-like Co/Mo-MOF with mesoporous alleviated the aggregation of CdS NPs while simultaneously fostering reactant-active site contact and improving the reactant-product transport rate. This allowed the material to act as a novel co-reaction accelerator, speeding up the transformation of the SO into SO and enhancing the cathodic ECL emission of g-CN.
View Article and Find Full Text PDFGels
November 2024
Department of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country, UPV/EHU, Apartado 644, E-48080 Bilbao, Spain.
This study presents the development of zirconium polycarboxylate gel systems as substrates for advanced fluorescence sensing devices. Zirconium-based metal-organic gels (MOGs) offer a promising alternative due to the robustness of the Zr-O bond, which provides enhanced chemical stability. In this work, zirconium polycarboxylate gels were synthesized using green solvents in a rapid room temperature method.
View Article and Find Full Text PDFChemistry
December 2024
Huazhong University of Science and Technology, School of Materials Science and Engineering, CHINA.
Metal nanoclusters (NCs) with dimensions of approximately 3 nm serve as a crucial link between metal-organic complexes and metal nanoparticles, garnering significant interest due to their distinctive molecule-like characteristics. These include well-defined molecular structures, clear HOMO-LUMO transitions, quantized charge, and robust luminescence emission. Atomically precise alloy NCs, in contrast to homometallic NCs, exhibit a wealth of structures and intriguing properties, with their novel attributes often intricately tied to the positions of alloyed elements within the structure, facilitating the exploration of structure-property relationships.
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