Synthesis and crystallographic characterization of NO-CH-I(NTf) (NTf = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf) is unable to and theoretical analysis indicates Ar-I(NTf) is the most oxidizing in the ArIL class of compounds known and may also be the most oxidizing compound in the class practically possible.
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| http://dx.doi.org/10.1039/d3cc04563c | DOI Listing |
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