The factors affecting the mechanical strength of coal and coal charges, deviations of the crushing capacity coefficients' actual values of coal charges from their calculated values, and the possibility of categorizing coal in relation to the degree of its resistance to crushing have been explored. The dependence permitting satisfactory precognition of the HGI value of the coal charge placed on the data of the crushing capacity coefficients of its ingredients was settled. The effect of the grinding ability of coal on its quality indicators, namely the degree of metamorphism, petrographic and elemental composition has been examined in this article. Determination of the coal grind ability was made by means of widely known Protodyakonov and Hardgrove methods, which allow estimating the resistibility of the material to the grind forces. For research 14 samples of coals (Ukraine, USA, and Kazakhstan), and 7 testers of coal charges at the basic coke chemical companies of Ukraine, were applied. The graphical and mathematical dependences are stated to have been developed to enable the predicting of the grinding ability of coals using the Hardgrove (HGI) and Protodyakonov (f) methods, based on determining the indicators of their quality (C, R, O, V). It is shown that the graphical and mathematical dependencies are polynomials of the second degree, and the values of the coefficients of determination (R) exceed 0.550-0.930. For the initial time, the coherency between the strength coefficient according to the Protoyakonov method and coal pulverization to the Hardgrove method was established. It was found the f and HGI values of measure are inversely in proportion, and a mathematical and diagram dependence based on one of them for its prognosticate has been established.
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http://dx.doi.org/10.1016/j.heliyon.2023.e20841 | DOI Listing |
Food Res Int
November 2024
Department of Agricultural, Food, Environmental and Animal Sciences, University of Udine, Via Sondrio 2/A, 33100 Udine, Italy.
Cryogel particles were obtained by freeze-drying and grinding hydrogel monoliths made from 20 % (w/w) whey protein isolate (WP) suspensions prepared at different pH (pH 4.8, 5.7, and 7.
View Article and Find Full Text PDFChemistry
November 2024
Main group Organometallics Optoelectronic Materials and Catalysis lab, Department of Chemistry, National Institute of Technology, Calicut, 673601, India.
In this study, we report the design and synthesis of two novel carbazole-based bis-cyanostilbenes incorporating phenyl and thiophene π-spacer units to investigate their distinct impacts on photophysical properties. Notably, the thiophene-based derivative exhibits remarkable far-red/near-infrared (NIR) solid-state emission, with an emission peak at 732 nm, which shifts to 750 nm upon mechanical grinding, demonstrating pronounced mechanochromic fluorescence in the NIR region. Although its quantum yield is moderate, the ability to modulate its emission through mechanical stimuli opens exciting opportunities for stimuli-responsive NIR applications.
View Article and Find Full Text PDFChemistry
November 2024
Department of Chemical Sciences, Tezpur University, Napaam, Sonitpur, Assam, 784 028, India.
Polymorphism and its screening to select the best-performing form is in high demand. In low molecular weight organogels (LMWG), gelators are designed as they contain flexible groups, functionalities capable of varied H-bonding, and increased the potential to show polymorphism. We synthesized a bis-urea based LMWG G1 and isolated three distinct polymorphic phases (Form I, II, and III).
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
State Key Laboratory of Oral Diseases, National Clinical Research Center for Oral Diseases, Department of Prosthodontics, West China Hospital of Stomatology, State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu, 610041, China.
Currently, the diagnosis of malocclusion is a highly demanding process involving complicated examinations of the dental occlusion, which increases the demand for innovative tools for occlusal data monitoring. Nevertheless, continuous wireless monitoring within the oral cavity is challenging due to limitations in sampling and device size. In this study, by embedding high-performance piezoelectric sensors into the occlusal surfaces using flexible printed circuits, a fully integrated, flexible, and self-contained transparent aligner is developed.
View Article and Find Full Text PDFNat Commun
October 2024
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240, PR China.
The intricate balance among cost, output, and quality has substantially hindered the practical application of graphene within the downstream industry chain. Here we present a scalable and green supercritical CO-assisted mechano-exfoliation (SCME) process that omits the use of organic solvents and oxidants throughout the production lifecycle, including exfoliation, separation, and purification. The SCME process achieves graphene powder space-time yields exceeding 40 kg/(m³·day) at laboratory (0.
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