Asymmetric Chemical Potential Activated Nanointerfacial Electric Field for Efficient Vanadium Redox Flow Batteries.

ACS Nano

Shenzhen Key Laboratory of New Lithium-ion Batteries and Mesoporous Materials, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.

Published: November 2023

Constructing active sites with enhanced intrinsic activity and accessibility in a confined microenvironment is critical for simultaneously upgrading the round-trip efficiency and lifespan of all-vanadium redox flow battery (VRFB) yet remains under-explored. Here, we present nanointerfacial electric fields (-fields) featuring outstanding intrinsic activity embodied by binary MoC-MoN sublattice. The asymmetric chemical potential on both sides of the reconstructed heterogeneous interface imposes the charge movement and accumulation near the atomic-scale N-Mo-C binding region, eliciting the configuration of an accelerator-like -field from MoN to MoC sublattice. Supported with theoretical calculations and intrinsic activity tests, the improved vanadium ion adsorption behavior and charge-transfer process at the nanointerfacial sites were further substantiated, hence expediting the electrochemical kinetics. Accordingly, the pronounced promotion is achieved in the resultant flow battery, yielding an energy efficiency of 77.7% and an extended lifespan of 1000 cycles at 300 mA cm, outperforming flow cells with conventional single catalysts in most previous reports.

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http://dx.doi.org/10.1021/acsnano.3c07732DOI Listing

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