AI Article Synopsis
- * The study contrasts the effects of nitrogen functionalities against textural properties in four types of activated carbons to determine their influence on ORR activity.
- * Results indicate that N-doping plays a more critical role than textural properties in these carbon materials, contributing to ongoing discussions in the carbon research community.
Article Abstract
Nitrogen-doped carbon-based electrodes are among the most promising alternatives to platinum-based electrodes in the cathode of fuel cells and metal-air batteries, where the oxygen reduction reaction (ORR) takes place. Among the approaches for improving ORR activity, nitrogen functionalities and well-developed textural properties have proved very effective. Nonetheless, the question of which between nitrogen active sites or textural properties are more crucial in N-doped carbon materials remains unanswered. This work proposes a comparative and critical approach through the selective functionalization of four commercial activated carbons with different textural properties. This study highlights the greater importance of N-doping in relation to the textural properties of carbon materials, and provides fundamental insights for conclusively addressing the ongoing debate within the carbon community about the significance of these two factors in the context of ORR.
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| http://dx.doi.org/10.1016/j.jcis.2023.10.013 | DOI Listing |
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