Truncated octahedral spinel LiMnO was homogenously coated by amorphous carbon layer chemical vapor deposition (CVD) using acetylene gas (CH) as carbon source to ease Mn dissolution to improve high-temperature performance, delivering a capacity retention of 92.9% after 1000 cycles at 5C at 50 °C.
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http://dx.doi.org/10.1039/d3cc04119k | DOI Listing |
Int J Mol Sci
December 2024
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China.
LiMnO, a significant cathode material for lithium-ion batteries, has garnered considerable attention due to its low cost and environmental friendliness. However, its widespread application is constrained by its rapid capacity degradation and short cycle life at elevated temperatures. To enhance the electrochemical performance of LiMnO, we employed a liquid-phase co-precipitation and calcination method to incorporate Cr into the LiMnO cathode material, successfully synthesizing a series of LiCrMnO (x = 0~0.
View Article and Find Full Text PDFNanoscale
December 2024
Department of Physics, SRM University - AP, Amaravati 522 240, Andhra Pradesh, India.
J Phys Chem C Nanomater Interfaces
October 2024
Department of Physical and Life Sciences, University of Huddersfield, Queensgate, Huddersfield HD1 3DH, U.K.
Nanocrystalline ceria exhibits significant redox activity and oxygen storage capacity. Any factor affecting its morphology can tune such activities. Strain is a promising method for controlling particle morphology, whether as core@shell structures, supported nanoparticles, or nanograins in nanocrystalline ceria.
View Article and Find Full Text PDFJ Am Chem Soc
November 2024
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Photogenerated charge separation is pivotal for effecting efficient photocatalytic reactions. Understanding this process with spatiotemporal resolution is vital for devising highly efficient photocatalysts. Here, we employed pump-probe transient reflection microscopy to directly observe the temporal and spatial evolution of photogenerated electrons and holes on the surface of facet-engineered bismuth vanadate (BiVO) crystals.
View Article and Find Full Text PDFLangmuir
October 2024
Energy Nano R&D Center, Korea Institute of Industrial Technology (KITECH), 6, Cheomdan-gwagiro 208-gil, Buk-gu, Gwangju 61012, South Korea.
Lithium nickel manganese oxide (LiNiMnO, LNMO) provides an elevated operating potential of 4.7 V and a theoretical capacity of 147 mAh g, without the need for expensive cobalt. Zr-doped LNMO was synthesized using the coprecipitation technique with Couette-Taylor flow.
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