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Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals. | LitMetric
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Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals.

Mehdi Elsayed Moussa Eva-Maria Rummel Maria Eckhardt Christoph Riesinger Manfred Scheer

Dalton Trans

Department of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany.

Published: November 2023

AI Article Synopsis

  • The reaction of various RCP compounds with Co(CO) and Fe(CO) under mild conditions resulted in unexpected breakage of the CP triple bond.
  • This fragmentation led to the formation of complex clusters, including a dimer based on cobalt with phosphorus and alkyl groups.
  • Additionally, an iron-containing cluster with a phosphorus and alkyl core was created during the reaction process.

Article Abstract

The reaction of RCP (R = Me, Bu, iPr) with Co(CO) and Fe(CO) under mild conditions led to unpredictable fragmentations of the CP triple bond and subsequent formation of clusters with a dimeric CoE (E = P and RC) and an FeP(CR) core, respectively.

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 Source
http://dx.doi.org/10.1039/d3dt02472eDOI Listing

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