Redox reaction of the monovalent Rh(CO)Cl and Bi ( = 2, 3) from KBi in ethylenediamine () solution produced the decabismuthide-hexarhodium dianion [Rh@Bi(RhCO)] (1a) wherein a novel Bi-bowl was constructed from oxidized 2Bi/2Bi open triangles/dimers, which was stabilized by strong bonding to a reduced Rh@(RhCO) square pyramid. Two 1a dianons are held together by weak interactions (van der Waals forces and spatial resistance) to form a dimer [Rh@Bi(RhCO)] (1). The structure and bonding of the novel polybismuthide heteroanion 1 are discussed.
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Dimeric polybismuth heteroanion of [Rh@Bi(RhCO)] constructed using Bi-bowl and square pyramidal Rh@(Rh-CO).
Dalton Trans
November 2023
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Redox reaction of the monovalent Rh(CO)Cl and Bi ( = 2, 3) from KBi in ethylenediamine () solution produced the decabismuthide-hexarhodium dianion [Rh@Bi(RhCO)] (1a) wherein a novel Bi-bowl was constructed from oxidized 2Bi/2Bi open triangles/dimers, which was stabilized by strong bonding to a reduced Rh@(RhCO) square pyramid. Two 1a dianons are held together by weak interactions (van der Waals forces and spatial resistance) to form a dimer [Rh@Bi(RhCO)] (1). The structure and bonding of the novel polybismuthide heteroanion 1 are discussed.
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