The levels of metals in the waters of the Mar Menor lagoon are higher in the southern than in the northern zone both in the dissolved (As: 1.78 μg L north vs 1.86 μg L south; Cd: 0.020 μg L vs 0.055 μg L; Pb: 0. 686 μg L vs 2.714 μg L; Zn: 3.06 μg L vs 10.2 μg L) as in the particulate fraction (As: 13.6 μg g north vs 27.3 μg g south; Cd: 0.510 μg g vs 2.11 μg g; Pb: 146 μg g vs 575 μg g; Zn: 266 μg g vs 729 μg g). This difference is associated to the influence of historical and recent inputs from the Sierra Minera Cartagena -La Unión located south of the lagoon. Strong winds cause sediment resuspension in this shallow lagoon, increasing metal levels in the dissolved (twofold) and especially in the particulate fraction (threefold) because the resuspended sediments are rich in metals. Distribution among dissolved and particulate fraction is determined by the chemistry of each element and salinity. This increase causes the levels to reach limits very close to those established by the Water Framework Directive, especially in the case of lead, whose annual average level of 1.23 μg L is very close to the 1.3 μg L established in the Directive. Therefore, slight change in environmental variables could make Pb levels to exceed legal limits. Future work should focus on investigating how unique environmental events, enhanced by global change, affect metal cycles in highly anthropised coastal areas.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.scitotenv.2023.167806 | DOI Listing |
Rapid Commun Mass Spectrom
April 2025
Department of Earth and Environmental Sciences, Indiana University Indianapolis, Indianapolis, Indiana, USA.
Rationale: Fog, dew, and rain are crucial for sustaining ecosystem functions, especially in water-limited regions. However, they are subject to isotopic changes during storage due to their usual small sample volumes and inherent sensitivity to atmospheric particulates. Understanding long-term storage effects on these water samples is essential for ensuring isotopic integrity.
View Article and Find Full Text PDFTher Clin Risk Manag
January 2025
Department of Nephrology and Clinical Poison Center, Chang Gung Memorial Hospital, Linkou Medical Center, Taoyuan, Taiwan, Republic of China.
Background: The negative impacts of particulate matter with an aerodynamic diameter of 2.5 μm or less (PM) are well known. Patients undergoing maintenance hemodialysis (HD) have significantly higher blood cadmium levels (BCLs) than healthy individuals.
View Article and Find Full Text PDFPLoS One
January 2025
Environmental Molecular Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, United States of America.
Coastal wetlands, including freshwater systems near large lakes, rapidly bury carbon, but less is known about how they transport carbon either to marine and lake environments or to the atmosphere as greenhouse gases (GHGs) such as carbon dioxide and methane. This study examines how GHG production and organic matter (OM) mobility in coastal wetland soils vary with the availability of oxygen and other terminal electron acceptors. We also evaluated how OM and redox-sensitive species varied across different size fractions: particulates (0.
View Article and Find Full Text PDFPharmaceutics
November 2024
Division of Biological Chemistry and Biologicals, National Institute of Health Sciences, 3-25-26 Tonomachi, Kawasaki-ku, Kawasaki 210-9501, Kanagawa, Japan.
Extracellular vesicles (EVs), including exosomes, are promising pharmaceutical modalities. They are purified from cell culture supernatant; however, the preparation may contain EVs with the desired therapeutic effects and different types of EVs, lipoproteins, and soluble proteins. Evaluating the composition of particulate impurities and the levels of protein impurities in final preparations is critical for quality control.
View Article and Find Full Text PDFAntioxidants (Basel)
November 2024
Departamento de Ingenierías Química y Biomolecular, Universidad de Cantabria, Avenida Los Castros, s/n, 39005 Santander, Cantabria, Spain.
With the rationale that the oxidative potential of particulate matter (PM-OP) may induce oxidative stress and inflammation, we conducted the ASTHMA-FENOP study in which 44 asthmatic patients and 37 matched controls wore a personal sampler for 24 h, allowing the collection of fine and coarse PM fractions separately, to determine PM-OP by the dithiothreitol (DTT) and ascorbic acid (AA) methods. The levels of Interleukin 6 (IL-6) and the IL-6/IL-10 ratio, as indicators of pro- and anti-inflammatory statuses, were determined by calculating the mean differences (MDs), odds ratios (ORs) and p-trends adjusted for sex, age, study level and body mass index. Positive associations for IL-6 levels in the form of adjusted MDs and ORs were obtained for all PM-OP metrics, reaching statistical significance for both OP-DTT and OP-AA in the fine fraction, with adjusted OR = 5.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!