Metamaterials are architected cellular materials, also known as lattice materials, that are inspired by nature or human engineering intuition, and provide multifunctional attributes that cannot be achieved by conventional polymeric materials and composites. There has been an increasing interest in the design, fabrication, and testing of polymeric metamaterials due to the recent advances in digital design methods, additive manufacturing techniques, and machine learning algorithms. To this end, the present review assembles a collection of recent research on the design, fabrication and testing of polymeric metamaterials, and it can act as a reference for future engineering applications as it categorizes the mechanical properties of existing polymeric metamaterials from literature. The research within this study reveals there is a need to develop more expedient and straightforward methods for designing metamaterials, similar to the implicitly created TPMS lattices. Additionally, more research on polymeric metamaterials under more complex loading scenarios is required to better understand their behavior. Using the right machine learning algorithms in the additive manufacturing process of metamaterials can alleviate many of the current difficulties, enabling more precise and effective production with product quality.
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http://dx.doi.org/10.3390/polym15193858 | DOI Listing |
Soft Matter
January 2025
Department of Physical Chemistry, Complutense University of Madrid, Av. Complutense s/n, 28040 Madrid, Spain.
We present a neo-Hookean elasticity theory for hybrid mechano-active hydrogels, integrating motor proteins into polymer meshes to create composite materials with active softening due to modulable chain overlaps. Focusing on polyacrylamide (PA) hydrogels embedded with FtsZ, a bacterial cytokinetic protein powered by GTP, we develop a multiscale model using microscopic Flory theory of rubbery meshes through mesoscopic De Gennes' scaling concepts for meshwork dynamics and phenomenological Landau's formalism for second-order phase transitions. Our theoretical multiscale model explains the active softening observed in hybrid FtsZ-PA hydrogels by incorporating modulable meshwork dynamics, such as overlapping functionality and reptation dynamics, into an active mean-field of unbinding interactions.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Mechanical Engineering, Sharif University of Technology, Tehran, Iran.
Lattice structures are an innovative solution to increase the strength-to-weight ratio of a structure. In this study, two polymeric hybrid lattice structures-"FRB" (a heterogenous structure which is indeed a BCC structure reinforced by FCC unit cells dispersed in a way to form a chessboard pattern in each layer) and the "Multifunctional" (a homogenous structure whose unit cells are a combination of FCC and BCC unit cells where their central nodes are connected)-are proposed, fabricated via liquid crystal display 3D printing technique, and their mechanical characteristics are evaluated under quasi-static loading, experimentally and numerically. The results indicate a 15.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Optical vortices possess a helical phase wavefront with central phase dislocation and orbital angular momentum. We demonstrated three-dimensional microstructure formation using a femtosecond optical vortex beam. Two-photon polymerization of photocurable resin was induced by long-term exposure, resulting in the fabrication of cylindrical structures.
View Article and Find Full Text PDFJ Chem Phys
December 2024
Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Amsterdam, The Netherlands.
In simulations, particles are traditionally treated as rigid platforms with variable sizes, shapes, and interaction parameters. While this representation is applicable for rigid core platforms, particles consisting of soft platforms (e.g.
View Article and Find Full Text PDFBiofabrication
December 2024
Technical University of Darmstadt, Institute for BioMedical Printing Technology, Magdalenenstr. 2, 64289 Darmstadt, Germany.
3D-bioprinting is a promising technique to mimic the complex anatomy of natural tissues, as it comprises a precise and gentle way of placing bioinks containing cells and hydrogel. Although hydrogels expose an ideal growth environment due to their extracellular matrix (ECM)-like properties, high water amount and tissue like microstructure, they lack mechanical strength and possess a diffusion limit of a couple of hundred micrometers. Integration of electrospun fibers could hereby benefit in multiple ways, for instance by controlling mechanical characteristics, cell orientation, direction of diffusion and anisotropic swelling behavior.
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