The application of organic coatings is a common way of protecting metal substrates against corrosion. To dry the coating faster, catalytic infrared radiation (IR) can be applied. This paper aims to assess the differences in the physical, chemical, and corrosion properties of primer coatings dried with catalytic infrared radiation, compared to the same coatings dried under atmospheric conditions. Corrosion properties were characterized using humidity and a salt spray chamber, as well as electrochemical impedance spectroscopy (EIS), preceded by open circuit potential (OCP) measurement. Pencil hardness, cross-cut, and pull-off adhesion tests were used to compare the properties of examined primers before and after testing in the corrosion acceleration chambers. The microstructure and distribution of chemical composition were studied by scanning electron microscope (SEM) with energy-dispersive X-ray spectroscopy (EDX) together with Fourier-transform infrared spectroscopy (FTIR). Phase transitions in the coating were determined by differential scanning calorimeter (DSC). Infrared-dried primers achieved a higher curing degree. Therefore, their mechanical and corrosion properties are superior when compared to the same coatings dried under atmospheric conditions.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10573800PMC
http://dx.doi.org/10.3390/ma16196551DOI Listing

Publication Analysis

Top Keywords

catalytic infrared
12
infrared radiation
12
corrosion properties
12
coatings dried
12
compared coatings
8
dried atmospheric
8
atmospheric conditions
8
properties
5
corrosion
5
influence catalytic
4

Similar Publications

Differences in Rejuvenation Mechanisms and Physical Properties of Aged Styrene-Butadiene-Styrene (SBS)-Modified Bitumen by Mono-Epoxy and Di-Epoxy Compounds.

Polymers (Basel)

December 2024

Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang'an University, South 2nd Ring Road Middle Section, Xi'an 710064, China.

Studying the mechanisms and effects of rejuvenators on SBS-modified bitumen is crucial for repairing degraded SBS and recycling aged SBS-modified bitumen (ASMB), thereby contributing to the sustainable development of bitumen pavements. This research examines the roles of mono-epoxy Alkyl (C12-C14) glycidyl ether (AGE) and di-epoxy 1,6-Hexanediol diglycidyl ether (HDE) under the catalysis of N,N-dimethyl benzyl amine (BDMA) in repairing degraded SBS chains. Aromatic oil (ORSMB)-, AGE-aromatic oil (ARSMB)-, and HDE-aromatic oil (HRSMB)-rejuvenated bitumen are analyzed for their chemical structures, physical properties, and rheological properties.

View Article and Find Full Text PDF

Laser Synthesis of Platinum Single-Atom Catalysts for Hydrogen Evolution Reaction.

Nanomaterials (Basel)

January 2025

Department of Materials, School of Natural Science, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.

Platinum (Pt)-based heterogeneous catalysts show excellent performance for the electrocatalytic hydrogen evolution reaction (HER); however, the high cost and earth paucity of Pt means that efforts are being directed to reducing Pt usage, whilst maximizing catalytic efficiency. In this work, a two-step laser annealing process was employed to synthesize Pt single-atom catalysts (SACs) on a MOF-derived carbon substrate. The laser irradiation of a metal-organic framework (MOF) film (ZIF67@ZIF8 composite) by rapid scanning of a ns pulsed infrared (IR; 1064 nm) laser across the freeze-dried MOF resulted in a metal-loaded graphitized film.

View Article and Find Full Text PDF

Biomass, though a major energy source, remains underutilized. Biochar from biomass pyrolysis, with its high porosity and surface area, is especially useful as catalyst support, enhancing catalytic activity and reducing electron recombination in photocatalysis. Indonesia, the world's top palm oil producer, generated around 12 million tons of empty fruit bunches (EFBs) in 2023, making EFBs a promising biochar source.

View Article and Find Full Text PDF

Molybdate, an oxidized form of molybdenum, facilitates molybdenum to be taken into cell, and thus to be included as a cofactor in the structure of enzymes necessary to ensure homeostasis. Although this compound provides the catalysis and electron transport of many biochemical reactions, it causes serious health problems in animals at high concentrations. For this reason, its recovery of water resources is one of the main subjects of scientific studies called bioremediaiton.

View Article and Find Full Text PDF

Resolving the Nanostructure of Carbon Nitride-Supported Single-Atom Catalysts.

Small

January 2025

Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy.

Single-atom catalysts (SACs) are gathering significant attention in chemistry due to their unique properties, offering uniform active site distribution and enhanced selectivity. However, their precise structure often remains unclear, with multiple models proposed in the literature. Understanding the coordination environment of the active site at the atomic level is crucial for explaining catalytic activity.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!