Purple crystals of the title compound, CHClNS were obtained from the reaction of 2,5-bis-(4-propyl-1-pyrrol-2-yl)thio-phene and 3,5-di-chloro-benzaldehyde in the presence of tri-fluoro-acetic acid for 3 h and subsequent addition of -chloranil. The macrocycle in the title compound can be described as a highly planar structure wthe the average deviation of the 32 macrocyclic atoms from the least-squares plane being 0.0416 Å. Its mol-ecular conformation is stabilized by two intra-molecular N-H⋯N bonds and a three-dimensional network is formed by C-H⋯π inter-actions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561226 | PMC |
| http://dx.doi.org/10.1107/S2414314623007666 | DOI Listing |
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