Objective: to investigate and compare the reinforcing effects of glass fibers (GFs) and ZrO nanoparticles at different ratios on the Flexural Strength (FS), Microhardness (MH), and Surface Roughness (SR) of autopolymerizing provisional PMMA.
Methods: A total of one hundred and twenty specimens of autopolymerizing PMMA were prepared for FS, MH, and SR tests and grouped as follows: no additives (control group), for the tested groups, different ratios of GFs and ZrO at 5% of autopolymerizing PMMA were incorporated. The ratios of GFs/ZrO nanoparticles were 0%-5%, 1%-4%, 2%-3%, 2.5%-2.5%, 3%-2%, 4%-1% and 5%-0% (n = 5). The FS was evaluated using the three-point bending test, MH was evaluated using the Vickers microhardness tester and SR was evaluated using a contact-type profilometer. Data were analyzed using ANOVA, Tukey's test, and Person correlation at 0.05 level of significance
Results: The unreinforced group had the lowest FS, MH, and SR mean values followed by (0%GFs + 5% ZrO), (1% GFs + 4% ZrO), (2% GFs + 3% ZrO), (2.5% GFs + 2.5% ZrO), (3% GFs + 2% ZrO), (4% GFs + 1% ZrO) and (5% GFs + 0% ZrO) which had the highest values.
Conclusion: Hybrid reinforcement with GFs, ZrO nanoparticles, or a combination of them effectively improved flexural strength and microhardness of autopolymerizing provisional PMMA that would create provisional restorations with extended clinical service. GFs demonstrated superior reinforcing effects compared to ZrO nanoparticles. However, reinforcement with 2.5-5% GFs increased the surface roughness for provisional restoration.
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http://dx.doi.org/10.1016/j.sdentj.2023.05.029 | DOI Listing |
Dalton Trans
January 2025
Departamento de Química Inorgánica, Facultad de Química y Farmacia, Centro de Energía UC, Centro de Investigación en Nanotecnología y Materiales Avanzados CIEN-UC, Pontificia Universidad Católica de Chile, Avenida Vicuña Mackenna, 4860, Santiago, Chile.
Recalcitrant pollutants are challenging to degrade during water treatment processes. Methylene blue (MB), a cationic dye, is particularly resistant to degradation and is environmentally persistent. Heterogeneous photocatalysis has emerged as a suitable strategy for removing such pollutants from water.
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December 2024
Songshan Lake Materials Laboratory (SLAB), Dongguan, 523808, P. R. China.
Aqueous zinc-ion batteries (AZIBs) stand out among many energy storage systems due to their many merits, and it's expected to become an alternative to the prevailing alkali metal ion batteries. Nevertheless, the cumbersome manufacturing process and the high cost of conventional separators make them unfavorable for large-scale applications. Herein, inspired by the unique nature of cellulose and ZrO, a Janus cellulose fiber (CF)/polyvinyl alcohol (PVA)/ZrO separator is prepared via the vacuum filtration method.
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December 2024
Green Carbon Research Center, Korea Research Institute of Chemical Technology, Daejeon, 34114, Republic of Korea.
Pentose oxidation and reduction, processes yielding value-added sugar-derived acids and alcohols, typically involve separate procedures necessitating distinct reaction conditions. In this study, a novel one-pot reaction for the concurrent production of xylonic acid and xylitol from xylose is proposed. This reaction was executed at ambient temperature in the presence of a base, eliminating the need for external gases, by leveraging Pt-supported catalysts.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400, United States.
Artificial N fixation via the electrocatalytic nitrogen (N) reduction reaction (NRR) has been recently promoted as a rational route toward reducing energy consumption and CO emission as compared with the traditional Haber-Bosch process. Nevertheless, optimizing NRR relies on developing highly efficient electrocatalysts. Herein, we report on the reliable and reproducible synthesis of two promising electrocatalysts in either the presence or absence of Ketjenblack (KB), namely, ZrO-ZrN@KB and ZrO-ZrN systems, synthesized through the nitriding of Zr.
View Article and Find Full Text PDFIndian J Microbiol
December 2024
Technical Institute of Baquba, Middle Technical University, Baquba, 32001 Iraq.
Research for novel compounds that may block bacterial development has continued and prompted by antibiotic-resistant bacteria. The expenses of community for health care as a result of antibiotic resistance has indeed been remarkable during the last decades and demand immediate of medical attention. Consequently, this research presents the antibacterial effect of genuine metal oxide nanoparticles against () and that have been isolated from urinary tract infection patients.
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